Aiming at the mobile user collaboration issue in mobile collaboration computing environment, another novel model, named MCUGFM (mobile collaboration user group forming model), was proposed based on our existed work. Based on the existed work, we also discussion about the cooperation requirement and cooperative ways of mobile user, the spatial-temporal factors and collaboration interest of cooperative mobile user were taken as the mainly matter formed the mobile collaborative group, under the specific character of mobile computing environment. Compared with previous user model, the MUGPFM is more embodying the essence characteristic of mobile users in a mobile collaboration group, because of the collaboration interest of cooperative mobile user, the services provided by platform and the ability of mobile user terminal divices were been considered respectively with different weight. So, the MUGPFM of this paper fit to the specific situation of mobile collaborative computing environment more than others. Nowadays, the MUGPFM was applied to the platform building that support the mobile collaboration services. The result indicated that the novel model has the correct semantic and the ability depicting effectively the formulation mechanism of mobile collaborative group in mobile collaboration.