2024
DOI: 10.1002/adfm.202416077
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A Multifunctional NaxBi/NaCl Flexible Interface Layer for Solid‐State Na Metal Batteries

Yifan Gu,
Hui Ma,
Xiaomeng Fan
et al.

Abstract: Na3Zr2Si2PO12 (NZSP) electrolyte with excellent air stability and acceptable ionic conductivity demonstrates a significant potential for application in solid‐state Na metal batteries. However, the poor interfacial contact between NZSP and Na anode has severely hindered its practical application. Herein, a BiCl3/polytetrafluoroethylene flexible interface layer is constructed between NZSP and Na metal anode. BiCl3 can react with Na metal to form a multifunctional NaxBi/NaCl‐rich flexible interface layer during t… Show more

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