A Multifunctional Dysprosium‐Carboxylato 2D Metall–Organic Framework

Abstract

We report the microwave assisted synthesis of a bidimensional (2D) MOF of formula [Dy(MeCOO)(PhCOO)2]n (1) and its magnetically diluted analogue [La0.9Dy0.1(MeCOO)(PhCOO)2] (1 d). 1 is a 2D material with single‐ion‐magnet (SIM) behaviour and 1 d is a multifunctional, magnetic and luminescent 2D material. 1 can be exfoliated into stable nanosheets by sonication.

Multifunctional lanthanide MOF luminescent sensor built by structural designing and energy level regulation of a ligand

“…As a new type of organic and inorganic hybrid material, metalorganic frameworks (MOFs) integrate metal ions and organic ligands by coordinated interactions and have been studied in lots of fields, including gas storage and separation, [1][2][3][4][5] heterogeneous catalysis, [6][7][8][9][10] proton conduction, [11][12][13][14][15] luminescence detection, [16][17][18][19][20][21][22] etc. MOFs have a huge specific surface area and dense pore channels that can be designed and controlled.…”

Photoinduced magnetic hysteresis in a cyanide-bridged two-dimensional [Mn2W] coordination polymer

“…8 Such molecular-based 2D magnets are easily designed and synthesized, and their magnetism can be controlled via tailorable structures, and more importantly, they are relatively stable at room temperature. Despite some groundbreaking examples, [9][10][11][12][13] synthesis of structurally and magnetically controlled 2D magnets, based on coordination polymers, remains a major research challenge. In particular, bistable systems, 14 the magnetic states of which are switchable under external stimuli, envisage promising alternatives to classical inorganic materials in the field of information processing and sensing devices.…”