Because
of a continuous increase in energy demands and environmental
concerns, a focus has been on the design and construction of a highly
efficient, low-cost, environmentally friendly, and noble-metal free
electrocatalyst for energy technology. Herein we report facile synthesis
of the mixed-valence trinuclear cobalt complex 1 by the
reaction of 2-amino-1-phenylethanol and CoCl2·6H2O in methanol as the solvent at room temperature. Further, 1 was reduced by using aqueous N2H4 as
a simple reducing agent, followed by calcination at 300 °C for
3 h, yielding a nitrogen-doped mixed phase cobalt [β-Co(OH)2 and CoO] nanocatalyst (N@MPCoNC). Both 1 and N@MPCoNC were characterized by various
physicochemical techniques. Moreover, 1 was authenticated
by single-crystal X-ray diffraction studies. The hybrid N@MPCoNC reveals a unique electronic and morphological structure, offering
a low overpotential of 390 mV for a stable current density of 10 mA
cm–2 with high durability. This N@MPCoNC showed excellent electrocatalytic as well as photocatalytic activity
for oxygen evolution reaction compared to 1.