A molecular view of single-atom catalysis toward carbon dioxide conversion
Xin Shang,
Xiaofeng Yang,
Guodong Liu
et al.
Abstract:We present critical advances in single-atom catalysis toward CO2 transformation and address crucial issues about SACs from a molecular point of view.
The designed AIO catalyst, uniquely featuring co-coordination with AcGlu and bis(benzimidazolium) units at the Pd center. The structure promotes the formation of NHC-CO2 and AcGlu-CO2 with a TOF of 3456 h−1 in reaction of CO2 and propargylic amine.
An important subject of porous organic materials is the capacity to access enantioselectivity owing to their high surface area, controllable pore size, and easy of functionalization. However, recyclability of enantio-separation...
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