March 30, 1999This is a preprint of a paper intended for publication in a journal or proceedings. Since changes may be made before publication, this preprint is made available with the understanding that it will not be cited or reproduced without the permission of the author.
PREPRINT
ABSTRACTLow energy density in conventional capacitors severely limits efforts to miniaturize power electronics and imposes design limitations on electronics in general. We have successfully applied physical vapor deposition technology to greatly increase capacitor energy density. The high dielectric breakdown strength we have achieved in alumina thin films allows high energy density to be achieved with this moderately low dielectric constant material. The small temperature dependence of the dielectric constant, and the high reliability, high resistivity, and low dielectric loss of Al 2 O 3 , make it even more appealing. We have constructed single dielectric layer thin film capacitors and shown that they can be stacked to form multilayered structures with no loss in yield for a given capacitance. Control of film growth morphology is critical for achieving the smooth, high quality interfaces between metal and dielectric necessary for device operation at high electric fields. Most importantly, high rate deposition with extremely low particle generation is essential for achieving high energy storage at a reasonable cost. This has been achieved by reactive magnetron sputtering in which the reaction to form the dielectric oxide has been confined to the deposition surface. By this technique we have achieved a yield of over 50% for 1 cm 2 devices with an energy density of 14 J per cubic centimeter of Al 2 O 3 dielectric material in 1.2 kV, 4 nF devices. By further reducing defect density and increasing the dielectric constant of the material, we will be able to increase capacitance and construct high energy density devices to meet the requirements of applications in power electronics.
INTRODUCTIONThe continuing miniaturization of power electronics demands further increases in energy storage density in capacitors. Applications such as switching power supplies, high frequency filter capacitors, variable speed electric motors, and pulsed power sources demand low loss, low inductance capacitors that tolerate high temperature.Nanostructure multilayer capacitors with interleaved films of conductor and dielectric make it possible to pack many thin dielectric layers in parallel. The key to achieving high energy density is making a dielectric layer that can support a very high field strength, since the energy density of the capacitor is proportional to the square of the field strength. To realize the high field strength of materials in a device, it is necessary to make large-area, defect free films, since any defect will lower the voltage at which the device will fail. While the electronics industry continues to develop multilayer ceramic capacitors by powder processing of ferroelectric materials we take a different approach and grow high quality ...