A Mn(iii)-catalyzed arylboronic acid-based cascade reaction via a nonclassical organometallic-radical mechanism
Hui-Min Qian,
Jian-Dong Zhang,
Shun-Jun Ji
et al.
Abstract:An efficient cascade reaction of arylboronic acids, o-cyanoaryl isocyanides, and indoles catalyzed by manganese(III) acetylacetonate which enables the construction of a series of 2-(1H-indol-3-yl)-2-phenylindolin-3-imines was developed. The transformation features high...
In this review, we summarize the latest developments and applications of Mn(OAc)3 in organic synthesis over the past decade, focusing on efforts to achieve milder reaction conditions while expanding the scope of synthesis possibilities.
In this review, we summarize the latest developments and applications of Mn(OAc)3 in organic synthesis over the past decade, focusing on efforts to achieve milder reaction conditions while expanding the scope of synthesis possibilities.
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