A mixed-type of azametallacrown containing [Mn6(pnhz)6(DMF)4(H2O)2] and [Mn6(pnhz)6(DMF)2(H2O)4] constructed by a flexible pentadentate ligand

Chen, Yuting; Dou, Jianmin; Li, Dacheng; Wang, Suna

doi:10.1016/j.inoche.2009.11.005

Inorganic Chemistry Communications

2010

DOI: 10.1016/j.inoche.2009.11.005

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A mixed-type of azametallacrown containing [Mn6(pnhz)6(DMF)4(H2O)2] and [Mn6(pnhz)6(DMF)2(H2O)4] constructed by a flexible pentadentate ligand

Yuting Chen

Jianmin Dou

Dacheng Li

et al.

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Cited by 12 publications

References 28 publications

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A Family of 12‐Azametallacrown‐4 Structural Motif with Heterometallic Mn^III‐Ln‐Mn^III‐Ln (Ln=Dy, Er, Yb, Tb, Y) Alternate Arrangement and Single‐Molecule Magnet Behavior

Yang

Cao

et al. 2015

Chemistry A European J

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Mixed 3d-4f 12-azametallacrown-4 complexes, [Mn2 Ln2 (OH)2 (hppt)4 (OAc)2 (DMF)2 ]⋅2 DMF⋅H2 O [Ln=Dy (1), Er (2), Yb (3), Tb (4) and Y (5), H2 hppt=3-(2-hydroxyphenyl)-5-(pyrazin-2-yl)-1,2,4-triazole)], were synthesized by reactions of H2 hppt with Mn(OAc)2 ⋅4 H2 O and Ln(NO3 )3 ⋅6 H2 O. This is the first 3d-4f azametallacrown family to incorporate Ln ions into the ring sets. These isostructural complexes exhibit alternating arrangements of two Mn and two Ln ions in the rings with each pair of metal centers bound by an NN group and μ2 -O bridging. Magnetic measurements revealed dominant antiferromagnetic interactions between metal centers, and frequency-dependent out-of-phase (${\chi {^\prime}{^\prime}_{\rm{M}} }$) signals below 4 K suggest slow relaxation of magnetization.

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A Family of 12‐Azametallacrown‐4 Structural Motif with Heterometallic Mn^III‐Ln‐Mn^III‐Ln (Ln=Dy, Er, Yb, Tb, Y) Alternate Arrangement and Single‐Molecule Magnet Behavior

Yang

Cao

et al. 2015

Chemistry A European J

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Synthesis, Crystal Structure and Properties of a New 3D Supramolecular Metal–Organic Framework with Stable Tunnels

Chai

Song

Lin

et al. 2012

J Inorg Organomet Polym

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Metallacrown-based compounds: Applications in catalysis, luminescence, molecular magnetism, and adsorption

Ostrowska

Fritsky

Gumienna‐Kontecka

et al. 2016

Coordination Chemistry Reviews

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A mixed-type of azametallacrown containing [Mn6(pnhz)6(DMF)4(H2O)2] and [Mn6(pnhz)6(DMF)2(H2O)4] constructed by a flexible pentadentate ligand

Cited by 12 publications

References 28 publications

A Family of 12‐Azametallacrown‐4 Structural Motif with Heterometallic Mn^III‐Ln‐Mn^III‐Ln (Ln=Dy, Er, Yb, Tb, Y) Alternate Arrangement and Single‐Molecule Magnet Behavior

A Family of 12‐Azametallacrown‐4 Structural Motif with Heterometallic Mn^III‐Ln‐Mn^III‐Ln (Ln=Dy, Er, Yb, Tb, Y) Alternate Arrangement and Single‐Molecule Magnet Behavior

Synthesis, Crystal Structure and Properties of a New 3D Supramolecular Metal–Organic Framework with Stable Tunnels

Metallacrown-based compounds: Applications in catalysis, luminescence, molecular magnetism, and adsorption

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A mixed-type of azametallacrown containing [Mn6(pnhz)6(DMF)4(H2O)2] and [Mn6(pnhz)6(DMF)2(H2O)4] constructed by a flexible pentadentate ligand

Cited by 12 publications

References 28 publications

A Family of 12‐Azametallacrown‐4 Structural Motif with Heterometallic MnIII‐Ln‐MnIII‐Ln (Ln=Dy, Er, Yb, Tb, Y) Alternate Arrangement and Single‐Molecule Magnet Behavior

A Family of 12‐Azametallacrown‐4 Structural Motif with Heterometallic MnIII‐Ln‐MnIII‐Ln (Ln=Dy, Er, Yb, Tb, Y) Alternate Arrangement and Single‐Molecule Magnet Behavior

Synthesis, Crystal Structure and Properties of a New 3D Supramolecular Metal–Organic Framework with Stable Tunnels

Metallacrown-based compounds: Applications in catalysis, luminescence, molecular magnetism, and adsorption

Contact Info

Product

Resources

About

A Family of 12‐Azametallacrown‐4 Structural Motif with Heterometallic Mn^III‐Ln‐Mn^III‐Ln (Ln=Dy, Er, Yb, Tb, Y) Alternate Arrangement and Single‐Molecule Magnet Behavior

A Family of 12‐Azametallacrown‐4 Structural Motif with Heterometallic Mn^III‐Ln‐Mn^III‐Ln (Ln=Dy, Er, Yb, Tb, Y) Alternate Arrangement and Single‐Molecule Magnet Behavior