A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts

Li, Cunyao; Wang, Wenlong; Li, Yan; Ding, Yunjie

doi:10.1007/s11705-017-1672-9

Cited by 68 publications

(47 citation statements)

References 89 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Hence, there is ag rowingi nterest to develop more economic technologies, which allow for quantitativec atalyst recycling. [6] In this respect, many research groups investigated both heterogeneous and immobilised homogeneous catalysts for the title reaction, mainly using rhodium, [7][8][9][10][11][12][13][14] but also cobalt systems [15][16][17] as well as otherm etals. [18][19][20][21][22][23] The main problem of all these catalysts is the leachingo fa ctive metal speciesf rom the support in the presence of CO.…”

Section: Introductionmentioning

confidence: 99%

Supported Cobalt Nanoparticles for Hydroformylation Reactions

Hertrich

Scharnagl

Pews‐Davtyan

et al. 2019

Chemistry A European J

View full text Add to dashboard Cite

Hydroformylation of olefinsh as been studied in the presence of specific heterogeneous cobalt nanoparticles. The catalytic materials were preparedb yp yrolysis of preformed cobalt complexes deposited ontod ifferent inorganic supports. Atomic absorption spectroscopy (AAS) measurements indicated ac orrelation of catalysta ctivity and cobalt leachinga sw ell as as trong influence of the heterogeneous support on the productivity.T hese new,l ow-cost, easy-tohandle catalystsc an substitute more toxic, unstablea nd volatile cobalt carbonylc omplexes for hydroformylations on a laboratory scale.

show abstract

Section: Introductionmentioning

confidence: 99%

Supported Cobalt Nanoparticles for Hydroformylation Reactions

Hertrich

Scharnagl

Pews‐Davtyan

et al. 2019

Chemistry A European J

View full text Add to dashboard Cite

show abstract

“…Hydroformylation in flow reactions has also been studied for industrial purposes [ 93 , 94 , 95 ]. Researchers at the University of Wisconsin-Madison and Eli Lilly Corporate Center published a paper on the asymmetric synthesis of ( S )-naproxen using rhodium-catalyzed hydroformylation, as shown in Scheme 26 [ 96 ].…”

Section: Recent Synthetic Advances In Naproxenmentioning

confidence: 99%

Recent Advances in the Synthesis of Ibuprofen and Naproxen

Paek

2021

Molecules

View full text Add to dashboard Cite

Herein, we review the recent progress in the synthesis of representative nonsteroidal anti-inflammatory drugs (NSAIDs), ibuprofen and naproxen. Although these drugs were discovered over 50 years ago, novel practical and asymmetric approaches are still being developed for their synthesis. In addition, this endeavor has enabled access to more potent and selective derivatives from the key frameworks of ibuprofen and naproxen. The development of a synthetic route to ibuprofen and naproxen over the last 10 years is summarized, including developing methodologies, finding novel synthetic routes, and applying continuous-flow chemistry.

show abstract

“…The catalysis of the hydroformylation process is constantly evolving with regard to the use of rhodium compounds as catalysts [ 84 ]. Even a rhodium single-atom exhibits catalytic activity in hydroformylation similar to the RhCl(PPh 3 ) 3 complex [ 85 ].…”

Section: Hydroformylation Reactionmentioning

confidence: 99%

Application of Coordination Compounds with Transition Metal Ions in the Chemical Industry—A Review

Malinowski

Zych

Jacewicz

et al. 2020

IJMS

View full text Add to dashboard Cite

This publication presents the new trends and opportunities for further development of coordination compounds used in the chemical industry. The review describes the influence of various physicochemical factors regarding the coordination relationship (for example, steric hindrance, electron density, complex geometry, ligand), which condition technological processes. Coordination compounds are catalysts in technological processes used during organic synthesis, for example: Oxidation reactions, hydroformylation process, hydrogenation reaction, hydrocyanation process. In this article, we pointed out the possibilities of using complex compounds in catalysis, and we noticed what further research should be undertaken for this purpose.

show abstract

A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts

Cited by 68 publications

References 89 publications

Supported Cobalt Nanoparticles for Hydroformylation Reactions

Supported Cobalt Nanoparticles for Hydroformylation Reactions

Recent Advances in the Synthesis of Ibuprofen and Naproxen

Application of Coordination Compounds with Transition Metal Ions in the Chemical Industry—A Review

Contact Info

Product

Resources

About