A Microporous Copper Metal–Organic Framework with High H₂ and CO₂ Adsorption Capacity at Ambient Pressure

A new carboxyl-copper-organic framework and its excellent selective absorbability for proteins

“…While in compound 1 here, the HL À ligands and Cu I ions connected to 3D sheet; on the other hand, residual carboxyl groups were formed in compound 1 here, and no big holes were found (a calculated porosity of about 1.1% according to PLATON). In compound 1, the Cu II centers presents two coordination modes [18], but in compound 1 here, the Cu I centers presents only one coordination mode. So a 3D pts topology is generated in compound 1 [18]; while an xfe-4-Fddd, (4 2 .6.8 3 ) topology was formed in compound 1 here.…”

“…In compound 1, the Cu II centers presents two coordination modes [18], but in compound 1 here, the Cu I centers presents only one coordination mode. So a 3D pts topology is generated in compound 1 [18]; while an xfe-4-Fddd, (4 2 .6.8 3 ) topology was formed in compound 1 here. Fig.…”

“…Compared to 1 3 [Cu(Me-4py-trz-ia)] from Lässig et al [18], a microporous MOF was formed by the Cu II centers and Me-4py-trzia 2 À ligands. While in compound 1 here, the HL À ligands and Cu I ions connected to 3D sheet; on the other hand, residual carboxyl groups were formed in compound 1 here, and no big holes were found (a calculated porosity of about 1.1% according to PLATON).…”

A Series of Robust Copper-Based Triazolyl Isophthalate MOFs: Impact of Linker Functionalization on Gas Sorption and Catalytic Activity †

“…Since the 1990s, metal-organic frameworks (MOFs) have emerged as an attractive class of porous materials for a broad spectrum of applications, like gas storage [1,2,3,4] and separation [5,6,7,8,9], as well as sensor design [10], biomedicine [11] and heterogeneous catalysis [12,13,14,15]. This versatile applicability derives from their large specific surface area, tunable properties, as well as their structural and chemical diversity [16,17].…”

Four transition metal complexes constructed with mixed mercaptotetrazole and 4,4′-bipyridine ligands

“…Several previous studies have shown that geometries and sizes of ligands, the coordinating ability of anions, and the nature of metals are all important in determining the structures of such complexes [3][4][5][6][7][8]. N-heterocycles with sulfhydryl ligands are capable of -N(H)-C(=S) $ -N=C(-SH) tautomerization.…”