A Method for Uniform Embedment and Self-Assembly of CIS-based QDs for Formation of Ordered QD Thin Films in PV Devices

Zheng, Yaxin; Sadeghimakki, Bahareh; Piano, Evan M.; Sivoththaman, Siva

doi:10.1109/pvsc40753.2019.8980483

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“…II-VI semiconductor group has potential applications in solar cell, light-emitting diodes and efficient thin film transistors [4]. Among thin-film systems, heterostructures of the CIS type [5][6], CIGS [7], CdTebased materials [8][9][10] have become the most effective. The expected effectiveness of the latter, in particular, reaches 28-30 % [11].…”

Section: Introductionmentioning

confidence: 99%

First-Principles Calculations of Stable Geometric Configuration and Thermodynamic Parameters of Cadmium Sulfide Thin-Film Condensates

Oleksyn

Naidych

Chernikova

et al. 2021

Phys. Chem. Solid St.

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Thin-film CdS layers obtained by the open evaporation method in vacuum are considered and cluster models for calculation of crystal, band structure and thermodynamic parameters are proposed. The thermodynamic parameters of the formation energy ΔE, enthalpy of formation ΔH, Gibbs energy ΔG, entropy ΔS and specific heat capacities at constant pressure and volume for cubic and hexagonal crystallographic modifications are determined. The stable crystal structure for cadmium sulfide was determined from the analysis of Gibbs energy temperature dependences for the sphalerite and wurtzine phases.

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