A Method for Manual Generation of Correct von Baeyer Names of Polycyclic Hydrocarbons

Eckroth, David R.

doi:10.1021/jo01286a600

Cited by 21 publications

(16 citation statements)

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“…RC-81.1.3.3 [9]. Deficiencies in the rules were pointed out by Eckroth [10] and RUcker & Rücker [11]. This document sets out to rectify such deficiencies and replaces the existing rules A-31, A-32 and B-14 [6].…”

Section: Extension and Revision Of The Von Baeyer System For Naming Pmentioning

confidence: 99%

Extension and revision of the von Baeyer system for naming polycyclic compounds (including bicyclic compounds)

Moss¹

1999

Pure and Applied Chemistry

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Names of countries given after members names are in accord with the JUPAC Handbook 1998-1 999.Republication or reproduction of this report or its storage and/or dissemination by electronic means is permitted without the need for formal IUPAC permission on condition that an acknowledgement, with full reference to the source along with use of the copyright symbol ©, the name IUPAC and the year of publication are prominently visible. Publication of a translation into another language is subject to the additional condition of prior approval from the relevant IUPAC National Adhering Organization. 513Unauthenticated Download Date | 5/9/18 8:05 PM

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Section: Extension and Revision Of The Von Baeyer System For Naming Pmentioning

confidence: 99%

Extension and revision of the von Baeyer system for naming polycyclic compounds (including bicyclic compounds)

Moss¹

1999

Pure and Applied Chemistry

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“…[7] The so-called Baeyer names of these compounds can be generated from a method created by Eckroth. [8] Since all diamondoids resemble parts of the hydrogen-terminated diamond lattice and because of their dimensions in the lower nanometer scale, these aliphatic hydrocarbon cage compounds are members of the carbon nanostructure family.…”

Section: Introductionmentioning

confidence: 99%

Diamonds are a Chemist's Best Friend: Diamondoid Chemistry Beyond Adamantane

2008

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Marilyn Monroe knew that "diamonds are a girl's best friend" but, in the meantime, many chemists have realized that they are also extremely attractive objects in contemporary chemistry. The chemist's diamonds are usually quite small (herein: nanometer-sized "diamondoids") and as a result of their unique structure are unusual chemical building blocks. Since lower diamondoids (up to triamantane) have recently become available in large amounts from petroleum and higher diamondoids (starting from tetramantane) are now also accessible from crude oil new research involving them has begun to emerge. Having well-defined structures makes these cage compounds so special compared to other nanometer-scale diamonds. Selective and high-yielding synthetic approaches to the functionalization of diamondoids gives derivatives that can find applications in, for example, polymers, coating materials, drugs, and molecular electronics.

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“…Diamantoide (alternativ auch “Polymantane” nach Balaban und Schleyer)7 haben jeweils eine exakt definierte Struktur (Abbildung 1). Balaban und Schleyer entwickelten auch eine Nomenklatur für die Diamantoide,7 während die jeweiligen Baeyer‐Namen nach einer Methode von Eckroth generiert werden können 8. Aufgrund der Tatsache, dass alle Diamantoide einen Ausschnitt des Wasserstoff‐terminierten Diamantgitters bilden und ihre Größen sich im unteren Nanometerbereich befinden, gehören diese aliphatischen Käfigverbindungen zur Familie der Kohlenstoffnanostrukturen (“carbon nanostructure family”).…”

Section: Introductionunclassified

“Diamonds are a chemist's best friend”: die großen Geschwister des Adamantans

2008

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Marilyn Monroe wusste: “Diamonds are a girl's best friend”, aber auch Chemiker haben Diamanten als attraktive Forschungsobjekte entdeckt. Dabei sind diese Diamanten normalerweise recht klein (hier nanometergroße “Diamantoide”) und stellen durch ihre einzigartigen Strukturen äußerst ungewöhnliche Synthesebausteine dar. Da es seit wenigen Jahren möglich ist, die “niederen” Diamantoide (bis zum Triamantan) in großen Mengen aus Erdöl zu erhalten, und da die Isolierung der “höheren” Diamantoide (ab Tetramantan) aus Rohöl ebenfalls technisch machbar ist, stehen diese somit der Forschung zur Verfügung. Die Diamantoide zeichnen sich gegenüber anderen nanometergroßen Diamanten besonders durch ihre klar definierten Strukturen aus. Durch zielgerichtete Funktionalisierungen mit hohen Ausbeuten lassen sich Derivate für sehr unterschiedliche Anwendungen wie z. B. Polymere, Oberflächenbeschichtungen, Medizin, molekulare Elektronik usw. herstellen.

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A Method for Manual Generation of Correct von Baeyer Names of Polycyclic Hydrocarbons

Cited by 21 publications

References 0 publications

Extension and revision of the von Baeyer system for naming polycyclic compounds (including bicyclic compounds)

Extension and revision of the von Baeyer system for naming polycyclic compounds (including bicyclic compounds)

Diamonds are a Chemist's Best Friend: Diamondoid Chemistry Beyond Adamantane

“Diamonds are a chemist's best friend”: die großen Geschwister des Adamantans

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