A method for estimating both the solubility parameters and molar volumes of liquids. Supplement

Fedors, R. F.

doi:10.1002/pen.760140611

Cited by 97 publications

(56 citation statements)

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“…U 2 was calculated using the Fedors' atom group contribution method [5,6]. Further, it was considered that v 2 varies under the effects of fluid density.Taking into account the fluid density-dependence, therefore, this was calculated by Equation 5 [7,8]:…”

Section: Correlationmentioning

confidence: 99%

“…(1) Kinematic viscosity is low, causing little stress (2) Excellent in permeability into micro-structure (3) Can control the solubility via the pressure and temperature (4) Low in environmental load because it is a component of atmospheric air (5) It is inert, nonflammable, nontoxic and odorless (6) Needs no drying process after washing metal masks Therefore, the solubility of organic compound into supercritical carbon dioxide was measured, and estimation of solubility was modeled. This solubility-estimating expression will be effective when we are designing a washing apparatus in the near future.…”

Section: Introductionmentioning

confidence: 99%

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A Study of Solubility of an Organic EL Compound by Means of Supercritical Carbon Dioxide

et al. 2005

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This study relates to the cleaning and reuse of metal masks used in the process of manufacturing organic EL displays, which belong to the next-generation display. Supercritical carbon dioxide was used as the solvent to wash those masks. In this study, the solubility of organic compound by supercritical carbon dioxide was measured, and modeling of solubility was completed. Focusing attention on the fact that the solubility is almost at the same level as that of RED60 dye, which is under development toward practical application, it was verified whether it was possible to thoroughly wash the mask, using mimic metal masks.

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Section: Correlationmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

A Study of Solubility of an Organic EL Compound by Means of Supercritical Carbon Dioxide

et al. 2005

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“…This solubility parameter 6 represents the cohesive energy density of the condensed phase (in this case the liquid), and it is related to the internal energy change upon vaporization AU by v "6 , 1 (11)(12)(13)(14)(15)(16)(17)(18)(19)(20)(21)(22)(23)(24) where V is the molar volume. …”

Section: Solvent Scan Theorymentioning

confidence: 99%

“…Statistical mechanics provides exact mixing rules for these coefficients: N Bm y y ijBij (11)(12) i,j and N Cm = Yi~j~k~ijk' (11-13) i,j,k 7 where N is the total number of components in the system. Expressions for $i valid for the gas chromatography case and for the piezoelectric sorption case will be presented along with the theory for each individual apparatus.…”

Section: S0vmentioning

confidence: 99%

“…(random-coil) (11)(12)(13)(14)(15)(16)(17)(18)(19)(20)(21) or, X 1 3 c=n -2 (rigid-rod) (11)(12)(13)(14)(15)(16)(17)(18)(19)(20)(21)(22) X 1 3 (= ln 1 1 + i (random-coil) (11)(12)(13)(14)(15)(16)(17)(18)(19)(20)(21)(22)(23) Here the last two equations show explicitly how the interaction parameter at infinite dilution of solvent can be obtained from gas chromatography if the density of the solvent and the polymer are known.…”

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confidence: 99%

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Polymer/Solvent and Polymer/Polymer Interaction Studies

Holste¹,

Glover²,

Magnuson³

et al. 1979

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Solubility of Polymers

Eckelt¹,

Eckelt²,

Wolf³

2011

Encyclopedia of Polymer Science and Technology

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Detailed knowledge concerning the phase state (homogeneous or coexistence of two or more condensed phases) of polymer containing mixtures is indispensible in virtually any area related to the production or application of macromolecules. In addition to this qualitative information it is for many purposes highly desirable to dispose of quantitative data regarding solvent quality or, more generally, with respect to the thermodynamic interaction between the components of the mixtures. This contribution starts with a brief presentation of the thermodynamic criteria deciding on the phase state and presents the experimental methods used in this area. The next section gives an overview on typical behaviors of polymer solutions and polymer blends; it is followed by a part recalling widely used theoretical approaches. Finally, a data section collects solvents and non‐solvents for a large number of polymers and presents some examples for the quantitative thermodynamic description of polymer solutions.

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A method for estimating both the solubility parameters and molar volumes of liquids. Supplement

Cited by 97 publications

References 1 publication

A Study of Solubility of an Organic EL Compound by Means of Supercritical Carbon Dioxide

A Study of Solubility of an Organic EL Compound by Means of Supercritical Carbon Dioxide

Polymer/Solvent and Polymer/Polymer Interaction Studies

Solubility of Polymers

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