“…Apart from palladium complexes containing ligands L15 , various mono‐, di‐ and trinuclear palladium(II) complexes were reported with the ligands L19 , L23 , L24 , L28 , L29 , and L30 (Figure ). [95f], [100c], [103f], Complex 115 2+ is a dicationic complex and is unique amongst all reported palladium‐triazolylidene complexes because of its double positive charge. [104a] Additionally, in contrast to the “normal” PEPPSI type complexes such as 113 , in complex 115 the pyridine rings are attached to the MIC ligands, making such complexes probably more sustainable than the PEPPSI type complexes 113 (where the monodentate pyridine ligands are known to dissociate from the complex during catalysis).…”