Abstract. The determination of salinity by means of electrical conductivity relies on a constant salt composition in the North Atlantic Ocean, as standard seawater, which is required for salinometer calibration, is produced therefrom. In order to verify the long-term constant composition of standard seawater, it was proposed to perform density measurements on standard seawater, as the seawater density is sensitive to all salt components. Thus, density measurements can detect any change in the composition of seawater. A conversion of the density values to salinity can be performed by means of a density–salinity relation. To use such a relation with a target uncertainty in salinity comparable to that in salinity obtained from conductivity measurements, a density measurement at an uncertainty level of 2 ppm is mandatory. In this article, a new density–salinity relation is presented based on such accurate density measurements. The underlying substitution measurement method is described, density corrections for uniform isotopic and chemical compositions are reported, and the density–salinity relation is presented. The comparison of densities calculated using the new relation with those calculated using the present reference equation of state TEOS-10 suggests that the density accuracy of TEOS-10 and that of some of its underlying density measurements are overestimated. The new density–salinity relation may be used to verify the constant composition of standard seawater by means of routine density measurements.