We find new technical unnaturalness in the standard model, which is a big cancellation between the order parameters for the chiral SU (2) and U (1) axial symmetries related each other at the quantum level of QCD. This unnaturalness can be made technically natural if massless new quarks with a new chiral symmetry is present, which is insensitive to the chiral SU (2) symmetry for the lightest up and down quarks. Thus QCD without such a chiral symmetry is technical unnatural, being shown to be extremely off the defined natural-parameter space. Hypothetical massless quarks might simultaneously solve the strong CP problem, together with the new technical naturalness problem. As one viable candidate, we introduce a dark QCD model with massless new quarks, which can survive current experimental, cosmological, and astrophysical limits, and also leave various phenomenological and cosmological consequences, to be probed in the future. The new unnaturalness can be tested in lattice QCD, gives a new avenue to deeper understand QCD, and provides a new guideline to consider going beyond the standard model.