Searching
for high-performance Ni-based cathodes plays an important
role in developing better aqueous nickel–zinc (Ni–Zn)
batteries. For this purpose, herein, we demonstrate the design and
synthesis of ultrathin α-Ni(OH)2 nanosheets branched
onto metal–organic frameworks (MOFs)-derived 3D cross-linked
N-doped carbon nanotubes encapsulated with tiny Co nanoparticles (denoted
as Co@NCNTs/α-Ni(OH)2), which are directly supported
on a flexible carbon cloth (CC). An aqueous Ni–Zn battery employing
the hierarchical CC/Co@NCNTs/α-Ni(OH)2 as the binder-free
cathode and a commercial Zn plate as the anode is fabricated, which
displays an ultrahigh capacity (316 mAh g–1) and
energy density (540.4 Wh kg–1) at 1 A g–1 as well as excellent rate capability (238 mAh g–1 at 10 A g–1) and superior cycling performance
(about 84% capacity retention after 2000 cycles at 10 A g–1). The impressive electrochemical performance might benefit from
the rich active sites, rapid electron transfer, cushy electrolyte
access, rapid ion transport, and robust structural stability. In addition,
the quasi-solid-state CC/Co@NCNTs/α-Ni(OH)2//Zn batteries
are also successfully assembled with polymer electrolyte, indicating
the great potential for portable and wearable electronics. This work
might provide important guidance for constructing carbon-based hybrid
materials directly supported on conductive substrates as high-performance
electrodes for energy-related devices.