Abstract:N-thiophthalimido-arylphenothiazines 2 and triarylamines 3 can be converted to dithiabridged triarylamine hetero[4]helicenes 1 using catalytic amounts of chalcogen substituted Lewis Bases and hexafluoro isopropanol as hydrogen bond donor. The procedure occurs under mild reaction conditions and gives good yields avoiding the use of excesses of Lewis Acids as previously reported. A preliminary study about the possibility to control the M and P absolute stereochemistry of helicenes 1 using enantiopure sulfur cont… Show more
Recyclable phenothiazine organophotoredox catalysts (PTHS 1–3, E1/2ox* = −2.34 to −2.40 V vs. SCE) have been developed. When the recycling performance was evaluated, PTHS-1 can be recovered at least four...
Recyclable phenothiazine organophotoredox catalysts (PTHS 1–3, E1/2ox* = −2.34 to −2.40 V vs. SCE) have been developed. When the recycling performance was evaluated, PTHS-1 can be recovered at least four...
Thiabridged [5]helicenes are obtained from thioary-N-phthalimido benzo[a]phenothiazines using a Hydrogen Brond Donor/Lewis Base organocatalytic approach. Resolution of [5]helicenes using either (1S)-(−)-camphanic acid as chiral auxiliary or CSP-HPLC is reported. Thiabridged...
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.