A kinetic study of oxidation of 1,4-dioxane by diperiodatonickelate(IV) in aqueous alkaline medium

Ruthenium(III) Catalysed Oxidation of L-Alanine by Alkaline Permanganate: A Kinetic and Mechanistic Approach

“…Such complex formation between substrate and catalyst has also been observed in earlier work [45][46][47][48][49]. This conclusion is supported by earlier observation [52][53][54] . The spectral evidence for complex formation between catalyst and substrate was obtained from the uv-vis spectra of the catalyst and a mixture of catalyst and aminoacid in the alkaline medium.…”

Synthesis and Characterisation of the Lithium, Sodium and Potassium Americium(β) Complexes of Hexaoxoperiodate: MI2[Am(OH)2H2IO6].xH2O

“…1,2 Recent work in this field has revealed that tetravalent lanthanide complexes of hexaoxoperiodate can be synthesised from solution. 3,4 A study has been undertaken to synthesise actinide compounds of hexaoxoperiodate, in which the less common oxidation states of actinides might be generated and stabilised.…”

Oxidation of 1,4‐Dioxane over Ti‐MWW in the Presence of H2O2

“…1,4-Dioxane displays infinite solubility in water; however, it is probably a carcinogen and hence classified as a hazardous compound and a priority pollutant. [1][2][3][4][5] If not removed from industrial waste water, it would contaminate groundwater and drinking water. Indeed, it has been detected in the surface and groundwater in the USA and Japan.…”

“…[12,13] This intermediate was also proposed by Notari [14] and observed by Zhao et al [15] On the other hand, it has been confirmed that oxidation of 1,4-dioxane with H 2 O 2 /O 3 occurs through a radical mechanism. [1,[3][4][5]16] Thus, we propose the following reaction pathway: First, hydrogen peroxide is decomposed homolytically to form a highly active HOC radical, which initializes the reaction [Eq. (1)].…”

“…The presence of HOC radicals was confirmed by a severe inhibition of the reaction in the presence of Na 2 CO 3 (Figure 2). CO 3 2À is well known to be a scavenger of HOC radicals as shown in Equation (5). [3,16] Figure 2 shows that when Na 2 CO 3 (0.5 mmol) was added to the reaction mixture, the H 2 O 2 -based conversion of 1,4-dioxane drastically decreased from 46 to 3.6 %.…”