A Highly Sterically Congested Bis‐Zinc‐Porphyrin Containing a Single Buta‐1,3‐diyne Linkage: From a Serendipitous Finding to Supramolecular Encapsulation
Abstract:A unique example of a bis‐zinc‐porphyrin chemical system in which both macrocycles are covalently connected with a single, short buta‐1,3‐diyne linkage placed at the ortho sites of the meso phenyl rings is presented. This dimeric compound resulted from an homo‐coupling side‐reaction taking place during a copper‐catalyzed click reaction between an alkyne porphyrin and 2‐azidopyridine derivatives. Its unexpected formation was rationalized by control experiments and an improved synthesis was achieved under copper… Show more
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