A highly ionic conductive poly(methyl methacrylate) composite electrolyte with garnet-typed Li6.75La3Zr1.75Nb0.25O12 nanowires

Sun, Jianqi; Li, Yaogang; Zhang, Qinghong; Hou, Chengyi; Shi, Qiuwei; Wang, Hongzhi

doi:10.1016/j.cej.2019.121922

Cited by 60 publications

(22 citation statements)

References 42 publications

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“…Meanwhile, PEO shows high viscosity, poor filmforming ability as well as narrow electrochemical window, which further hinder the LLZO-based/PEO SCEs for large scale application in real batteries. To explore LLZO-based/polymer SCEs with better properties, other novel types of polymers, such as poly(propylene carbonate) (PPC) [125][126][127][128] , poly(vinylidene fluoride) (PVDF) [129][130][131][132] , poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) [133][134][135][136][137] , poly(ethylene carbonate) (PEC) [138] , polyacrylonitrile (PAN) [139] , poly(methyl methacrylate) (PMMA) [140] , cross-linked polyethyleneglycol [141] , poly(ethylene glycol) diacrylate (PEGDA) [142] and mixed polymers [143][144][145] have been developed as the substrate for constructing novel LLZObased/polymer SCEs. Table 4 summarizes the intrinsic properties of the typical LLZO-based/novel polymer SCEs and the electrochemical performances of ASSLBs assembled by these novel SCEs.…”

Section: Llzo-based/novel Polymers Scesmentioning

confidence: 99%

Status and prospect of garnet/polymer solid composite electrolytes for all-solid-state lithium batteries

Deng

Chen

2020

Journal of Energy Chemistry

179

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Section: Llzo-based/novel Polymers Scesmentioning

confidence: 99%

Status and prospect of garnet/polymer solid composite electrolytes for all-solid-state lithium batteries

Deng

Chen

2020

Journal of Energy Chemistry

179

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“…For now, the mentioned fiber shaped LIB involved with lithium wire is still in its infancy because of the inevitable safety issues, just like the metallic activity and sensitivity of lithium to oxygen and humidity. Moreover, it is better to introduce safe electrolyte or solid electrolyte for the sake of wearable application [83,84]. Inspired by the emerging and efficient manufacturing process, as shown in Fig.…”

Section: Fiber-shaped Lithium Ion Batteriesmentioning

confidence: 99%

Advanced Functional Fiber and Smart Textile

et al. 2019

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The research and applications of fiber materials are directly related to the daily life of social populace and the development of relevant revolutionary manufacturing industry. However, the conventional fibers and fiber products can no longer meet the requirements of automation and intellectualization in modern society, as well as people's consumption needs in pursuit of smart, avant-grade, fashion and distinctiveness. The advanced fiber-shaped electronics with most desired designability and integration features have been explored and developed intensively during the last few years. The advanced fiber-based products such as wearable electronics and smart clothing can be employed as the second skin to enhance information exchange between humans and the external environment. In this review, the significant progress on flexible fiber-shaped multifunctional devices, including fiber-based energy harvesting devices, energy storage devices, chromatic devices, and actuators are discussed. Particularly, the fabrication procedures and application characteristics of multifunctional fiber devices such as fiber-shaped solar cells, lithium-ion batteries, actuators and electrochromic fibers are introduced in detail. Finally, we provide our perspectives on the challenges and future development of functional fiber-shaped devices.

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“…However, this process is time-intensive, energyconsuming, and difficult to scale up. For wet chemical processing, raw particles are first dispersed with a solvent to obtain a suspension with a target viscosity, and then SPEs are formed by solution casting (Sun et al, 2019), electrophoretic deposition (Blanga et al, 2015), or coating process (Park et al, 2006). The advantages of wet chemical processing are good wettability and high throughput (Liu et al, 2017).…”

Section: Solid Polymer/composite Electrolytesmentioning

confidence: 99%

Manufacturing Strategies for Solid Electrolyte in Batteries

Chen

Shi

et al. 2020

Front. Energy Res.

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Throughout the development of battery technologies in recent years, the solid-state electrolyte (SSE) has demonstrated outstanding advantages in tackling the safety shortcomings of traditional batteries while meeting high demands on electrochemical performances. The traditional manufacturing strategies can achieve the fabrication of batteries with simple forms (coin, cylindrical, and pouch), but encounter limitations in preparing complex-shaped or micro/nanoscaled batteries especially for inorganic solid electrolytes (ISEs). The advancement in novel manufacturing techniques like 3D printing has enabled the assembly of different solid electrolytes (polymeric, inorganic, and composites) in a more complex geometric configuration. However, there is a huge gap between the capabilities of the current 3D printing techniques and the requirements for battery production. In this review, we compare the traditional manufacturing to several novel 3D printing techniques, highlighting the potential of 3D printing in the SSE manufacturing. The latest SSE manufacturing progress in the group of direct-writing (DW) based or lithography-based printing technologies are summarized separately from the perspectives of feedstock selection, build envelope, printing resolution, and application (nano-scaled, flexible, and large-scale battery grids). Throughout the discussion, some challenges associated with manufacturing SSEs via 3D printing such as air/moisture sensitivity of samples, printing resolution, scale-up capability, and longterm sintering for ISEs have been put forward. This review aims to bridge the gap between 3D printing techniques and battery requirements by analyzing the existing limitation in SSE manufacturing and point out future needs.

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A highly ionic conductive poly(methyl methacrylate) composite electrolyte with garnet-typed Li6.75La3Zr1.75Nb0.25O12 nanowires

Cited by 60 publications

References 42 publications

Status and prospect of garnet/polymer solid composite electrolytes for all-solid-state lithium batteries

Status and prospect of garnet/polymer solid composite electrolytes for all-solid-state lithium batteries

Advanced Functional Fiber and Smart Textile

Manufacturing Strategies for Solid Electrolyte in Batteries

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