A hexanuclear Ni(II) complex of 1-[(2-carboxymethyl)benzene]-3-[2-pyridine] triazene

Li, Wei; Chen, Jin-Ye; Xu, Wei-Quan; He, Er-Xuan; Zhan, Shu‐Zhong; Cao, Derong

doi:10.1016/j.inoche.2011.03.030

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Materials and Physical Measurements1

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Cited by 12 publications

(1 citation statement)

References 22 publications

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“…The triazenido ligand, HL was prepared using a literature procedure [25]. Elemental analyses for C, H, and N were obtained on a Perkin-Elmer analyzer model 240.…”

Section: Materials and Physical Measurementsmentioning

confidence: 99%

A new molecular electro-catalyst based on a triazenido–cobalt complex for generating hydrogen from both acetic acid and water

Zhou

Zhan

2015

Catalysis Communications

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“…The triazenido ligand, HL was prepared using a literature procedure [25]. Elemental analyses for C, H, and N were obtained on a Perkin-Elmer analyzer model 240.…”

Section: Materials and Physical Measurementsmentioning

confidence: 99%

A new molecular electro-catalyst based on a triazenido–cobalt complex for generating hydrogen from both acetic acid and water

Zhou

Zhan

2015

Catalysis Communications

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BF₃·OEt₂‐Promoted Intramolecular Nucleophilic Substitution; Synthesis of Dibenzopyranones and Coumarins from Biaryltriazenes

Shang

Yang

et al. 2013

Eur J Org Chem

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Synthesis, Magnetic and Electrocatalytic Properties of a Dinuclear Triazendio‐Nickel(II) Complex

2017

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A new material both for magnetic coupling and electrocatalytic hydrogen production based on a dinuclear nickel(II) complex, [Ni 2 L 4 ] 1 has been prepared by the reaction of NiCl 2 ·6H 2 O and 1-[(2-methoxy) benzene]-3-[2-pyridine] triazene (HL). Magnetic analysis shows that in the solid state this nickel complex exhibits an antiferromagnetic exchange interaction between nickel(II) ions mediated by triazenido-bridges (J = À6.8 cm À1 ).In homogeneous environment, complex 1 shows electrocatalytic activities for hydrogen generation both from acetic acid and neutral buffer with a turnover frequency (TOF) of 101.25 moles of hydrogen per mole of catalyst per hour (mol H 2 /mol catalyst/h) at an overpotential (OP) of 941.6 mV and a TOF of 998.2 mol H 2 /mol catalyst/h at an OP of 836.7 mV, respectively.

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A hexanuclear Ni(II) complex of 1-[(2-carboxymethyl)benzene]-3-[2-pyridine] triazene

Cited by 12 publications

References 22 publications

A new molecular electro-catalyst based on a triazenido–cobalt complex for generating hydrogen from both acetic acid and water

A new molecular electro-catalyst based on a triazenido–cobalt complex for generating hydrogen from both acetic acid and water

BF₃·OEt₂‐Promoted Intramolecular Nucleophilic Substitution; Synthesis of Dibenzopyranones and Coumarins from Biaryltriazenes

Synthesis, Magnetic and Electrocatalytic Properties of a Dinuclear Triazendio‐Nickel(II) Complex

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A hexanuclear Ni(II) complex of 1-[(2-carboxymethyl)benzene]-3-[2-pyridine] triazene

Cited by 12 publications

References 22 publications

A new molecular electro-catalyst based on a triazenido–cobalt complex for generating hydrogen from both acetic acid and water

A new molecular electro-catalyst based on a triazenido–cobalt complex for generating hydrogen from both acetic acid and water

BF3·OEt2‐Promoted Intramolecular Nucleophilic Substitution; Synthesis of Dibenzopyranones and Coumarins from Biaryltriazenes

Synthesis, Magnetic and Electrocatalytic Properties of a Dinuclear Triazendio‐Nickel(II) Complex

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BF₃·OEt₂‐Promoted Intramolecular Nucleophilic Substitution; Synthesis of Dibenzopyranones and Coumarins from Biaryltriazenes