“…Background characterization can help managers set achievable management goals by accounting for site-specific background, including ambient conditions caused by atmospheric deposition. While background characterization is a widely accepted practice for soil, sediment, and groundwater assessment (e.g., ASTM, 2020;Battelle, 2012;EPA,1990EPA, , 2002aEPA, , 2002cEPA, , 2007ITRC, 2021), surface water background characterizations may get more scrutiny because of greater variability in chemical concentrations (and related water quality parameters), and because diffuse source contributions can be difficult to characterize. In flowing streams, sampling upstream of known or suspected sources is a simple way to conduct a background study.…”