A glimpse on all-solid-state Li-ion battery (ASSLIB) performance based on novel solid polymer electrolytes: a topical review

Arya, Anil; Sharma, Annu

doi:10.1007/s10853-020-04434-8

Cited by 73 publications

(45 citation statements)

References 187 publications

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“…Along with the non-flammable behavior of solid electrolytes, they can utilize Li-metal anodes and are able to effectively suppress the formation and growth of Li dendrites. Therefore, the solid-electrolyte strategy provides great opportunities to enhance the safety and energy density of lithium-based batteries [18,[84][85][86][87][88]. LiBH 4 has been considered as a promising solid-state electrolyte in recent years.…”

Section: Bismuth Chalcogenides As the Anode In All-solid-state Lithiumentioning

confidence: 99%

Implementation of Bismuth Chalcogenides as an Efficient Anode: A Journey from Conventional Liquid Electrolyte to an All-Solid-State Li-Ion Battery

et al. 2020

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Bismuth chalcogenide (Bi2X3; X = sulfur (S), selenium (Se), and tellurium (Te)) materials are considered as promising materials for diverse applications due to their unique properties. Their narrow bandgap, good thermal conductivity, and environmental friendliness make them suitable candidates for thermoelectric applications, photodetector, sensors along with a wide array of energy storage applications. More specifically, their unique layered structure allows them to intercalate Li+ ions and further provide conducting channels for transport. This property makes these suitable anodes for Li-ion batteries. However, low conductivity and high-volume expansion cause the poor electrochemical cyclability, thus creating a bottleneck to the implementation of these for practical use. Tremendous endeavors have been devoted towards the enhancement of cyclability of these materials, including nanostructuring and the incorporation of a carbon framework matrix to immobilize the nanostructures to prevent agglomeration. Apart from all these techniques to improve the anode properties of Bi2X3 materials, a step towards all-solid-state lithium-ion batteries using Bi2X3-based anodes has also been proven as a key approach for next-generation batteries. This review article highlights the main issues and recent advances associated with Bi2X3 anodes using both solid and liquid electrolytes.

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Section: Bismuth Chalcogenides As the Anode In All-solid-state Lithiumentioning

confidence: 99%

Implementation of Bismuth Chalcogenides as an Efficient Anode: A Journey from Conventional Liquid Electrolyte to an All-Solid-State Li-Ion Battery

et al. 2020

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“…Energy storage devices have been an inseparable part of the alternative energy sources used in the present generation. Electrolyte, the vital component of an energy storage device, plays a vital role in deciding various factors such as life span, working voltage, and specific capacity of the device 1,2 . Among the various classes of electrolytes used, polymer electrolytes are of focus in present‐day research.…”

Section: Introductionmentioning

confidence: 99%

Novel solid biopolymer electrolyte based on methyl cellulose with enhanced ion transport properties

Koliyoor

ISMAYIL

Hegde

et al. 2021

J of Applied Polymer Sci

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Magnesium ion conducting solid polymer electrolyte films are prepared with biodegradable methyl cellulose and Mg(NO3)2.6H2O by solution casting method. FTIR spectrum of the films confirmed the interaction between the polymer host and the metal salt. FTIR deconvolution gives a clear picture of the percentage of free ions with the salt concentration variation. Structural modification of the polymer upon salt doping are studied with XRD analysis. Glass transition temperature of the pristine film is found to increase with the concentration of the salt, which is attributed to an increase in the coordination between Mg+2 and oxygen atoms of the polymer matrix and formation of transient crosslinks. TGA analysis accounts for the thermal stability of the electrolyte films. The electrical properties of the films have been analyzed, and the values of ionic conductivities of the films were calculated. Electrolyte film with 25 wt% of the salt, which is highly amorphous, is found to have the highest room‐temperature ionic conductivity of 1.02 × 10−4 S cm−1. SEM micrographs show variation in the surface morphology of the electrolytes with the variation in the concentration of the salt. The films' electrochemical stability window and ionic transference number are calculated to find the suitability for energy storage applications.

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“…Figure 10 shows the possible structures of some of the dominating lithium salts in the R&D sector, and their key properties, that is, ionic conductivity, molecular weight, ion mobility, dissociation constant, and donor numbers are compared. Table 16 summarises the lithium salts for their anion sizes and main characteristics (ionic conductivity, molecular weight, ion mobility, dissociation constant, and donor numbers), which affects the electrolyte conductivity [303].…”

Section: Synthesis Methods For Cathode Materialsmentioning

confidence: 99%

Progress in electrode and electrolyte materials: path to all-solid-state Li-ion batteries

Sharma

Sharma²,

Gaur

et al. 2022

Energy Adv.

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A glimpse on all-solid-state Li-ion battery (ASSLIB) performance based on novel solid polymer electrolytes: a topical review

Cited by 73 publications

References 187 publications

Implementation of Bismuth Chalcogenides as an Efficient Anode: A Journey from Conventional Liquid Electrolyte to an All-Solid-State Li-Ion Battery

Implementation of Bismuth Chalcogenides as an Efficient Anode: A Journey from Conventional Liquid Electrolyte to an All-Solid-State Li-Ion Battery

Novel solid biopolymer electrolyte based on methyl cellulose with enhanced ion transport properties

Progress in electrode and electrolyte materials: path to all-solid-state Li-ion batteries

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