A Generalized Model for Describing Particle Formation in the Synthesis of Monodisperse Oxide Particles Based on the Hydrolysis and Condensation of Tetraethyl Orthosilicate
“…The sizes of silica spheres (the distance between the centers of adjacent spheres) prepared using ammonia and methylamine were 520 and 260 nm, and the surface area values were 7.6 and 15.8 m 2 g −1 , respectively. Surface area values were roughly corresponding to the calculated ones (6.1 and 12.2 m 2 g −1 ) based on the diameters (520 and 260 nm) and the density of silica spheres (1.87 g cm −3 ) [17]. SEM images and the surface area values indicate that silica spheres were nonporous.…”
Platinum metal particles having periodic macropores were prepared from close-packed silica spheres and an aqueous solution of hexachloroplatinum (IV) acid. The sizes of platinum macropores were controlled by the size of the silica spheres.
“…The sizes of silica spheres (the distance between the centers of adjacent spheres) prepared using ammonia and methylamine were 520 and 260 nm, and the surface area values were 7.6 and 15.8 m 2 g −1 , respectively. Surface area values were roughly corresponding to the calculated ones (6.1 and 12.2 m 2 g −1 ) based on the diameters (520 and 260 nm) and the density of silica spheres (1.87 g cm −3 ) [17]. SEM images and the surface area values indicate that silica spheres were nonporous.…”
Platinum metal particles having periodic macropores were prepared from close-packed silica spheres and an aqueous solution of hexachloroplatinum (IV) acid. The sizes of platinum macropores were controlled by the size of the silica spheres.
“…TEOS molar concentrations in Table 1 were calculated with reference to ethanol only. In the preparation of the large particles (sample D) in Table 1, CH 3 COOH was added to the system, as an increase in ionic strength increases resultant particle sizes in the hydrolysis of TEOS and is effective in suppressing generation of new particles in the seeded growth reaction [30,31].…”
Section: Suspension Of Surface-modified Silica Particlesmentioning
“…Monodisperse colloidal silica (SiO 2 ) spheres were prepared by a sol-gel method according to our previous papers [17,18]. A mixture of the methylamine solution (4.66 g), water (56.8 g), and ethanol (83.18 g) was placed in a water bath at 35 • C. Then the mixture was transferred to a flask that contained the TEOS (12.5 g) and the ethanol (100 g) at 35 • C under stirring.…”
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