A Fundamental Correlative Spectroscopic Study on Li1‐xNiO2 and NaNiO2
Quentin Jacquet,
Nataliia Mozhzhukhina,
Peter N.O. Gillespie
et al.
Abstract:The intricate relationship between local atomic arrangements and electronic states significantly influences the electrochemical properties of Li‐ion battery cathode materials. Despite decades of investigation, a consensus regarding the local atomic and electronic structure of LiNiO2 remains elusive. This ambiguity stems from the potential distortion of Ni sites, either via Jahn‐Teller (JT) distortion or bond disproportionation (BD), complicating the understanding of the charge compensation mechanism involving … Show more
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