Measurements of pVT made using the Burnett technique at (300
and 320) K are reported for methane,
ethane, three x
1 methane + (1 −
x
1) ethane mixtures with
x
1 = 0.30623, 0.49971, and 0.70090, and
two
x
1 methane + x
2 ethane
+ (1 − x
1 − x
2)
carbon dioxide mixtures with x
1 = 0.32125,
x
2 = 0.34099 and
x
1
= 0.24759, x
2 = 0.56013. Second virial
coefficients have been calculated from these results for the
pure
fluids, and the binary and ternary mixtures. Cross second and
third virial coefficients have been derived,
including the cross third virial coefficient which describes the
simultaneous unlike interaction between
methane, ethane, and carbon dioxide. The experimental results were
used to test an approximation to
the virial equation which greatly simplifies calculations for
multicomponent mixtures and which requires
only experimental virial coefficients for binary mixtures. Values
calculated using the model agree with
experimental values within the estimated uncertainties. The
results are compared with literature values,
where available.