A flame-retardant PET fabric coating: Flammability, anti-dripping properties, and flame-retardant mechanism

Tao, Ye; Liu, Chang; Li, Ping; Wang, Bin; Xu, Ying‐Jun; Jiang, Zhiming; Liu, Yun; Zhu, Ping

doi:10.1016/j.porgcoat.2020.105971

Cited by 55 publications

(27 citation statements)

References 58 publications

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“…There are many small bubbles on the surface of the carbon residue skeleton structure of CF-DETA-TA-PA, which is due to the decomposition of phytic acid to form phosphoric acid and pyrophosphate. (Tao et al 2021) 3.9 Infrared Analysis of Combustion Samples Fig. 3.8 shows the infrared spectra of CF and CF-DETA-TA-PA after combustion.…”

Section: Tg Analysismentioning

confidence: 99%

Preparation and Test of UV Resistant and Flame Retardant Cotton Fabric With Phytic Acid, Tannic Acid and Diethylenetriamine as Raw Materials

Zhou

Yin

Huang

et al. 2021

Preprint

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Although cotton fabric is widely used in various fields because of its unique advantages, it has the disadvantages of flammability and poor ultraviolet protection. By combining diethylenetriamine(DETA)、phytic acid (PA) and tannic acid(TA) on cotton fabric, a chemical reaction intumescent flame retardant cotton fabric with anti-ultraviolet and anti-flame retardant was developed. The flame retardant and ultraviolet resistance of cotton fabric were characterized by limiting oxygen index (LOI) test, vertical combustion test, cone calorimetry test and ultraviolet resistance test. Scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR) and other tests were used to analyze the chemical composition, surface morphology and residual carbon after combustion of the cotton fabric, and it was confirmed that the modified cotton fabric has good ultraviolet resistance and flame retardant performance. In this study, an eco-friendly cotton fabric treatment method was proposed, which made cotton fabric have anti-ultraviolet and flame retardant properties, and a new application of tannic acid and phytic acid in ultraviolet protection and flame retardant of fabric was put forward.

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Section: Tg Analysismentioning

confidence: 99%

Preparation and Test of UV Resistant and Flame Retardant Cotton Fabric With Phytic Acid, Tannic Acid and Diethylenetriamine as Raw Materials

Zhou

Yin

Huang

et al. 2021

Preprint

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Section: Introductionmentioning

confidence: 99%

“…Coating with different FRs have been used to prepare flame-retardant coating polyester (PET) fabrics. 6,7 The flame-retardant coating provides protection against fire, but it also braces and stiffens the textile, therefore improving fabric characteristics for upholstery usage. 8 Common FRs used for upholstery textile applications are based on halogenated compounds due to their high efficiency and the low dosages of FR needed in the formulation.…”

Section: Introductionmentioning

confidence: 99%

Graphite flame retardant applied on polyester textiles: flammable, thermal and in vitro toxicological analysis

Alonso

Manich

Campo

et al. 2022

Journal of Industrial Textiles

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Expandable graphite was applied to an upholstery polyester textile material as an eco-friendly flame-retardant alternative to halogenated compounds. Fabrics treated with the flame retardant were evaluated by flammability tests. Besides, thermal analysis was carried out by Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA). Moreover, a percutaneous absorption study was conducted to verify the safety in terms of dermal penetration of the flame-retardant treated upholstery fabric for human use. The upholstery fabric treated with expandable graphite successfully passed the flammability tests. Thermogravimetric analyses with TGA and DSC showed that the flame-retardant application slightly decreased the initial decomposition temperatures regardless of the atmosphere but increased the final residue at 600°C (35.7% in O2 and 44.5% in N2) compared to non-treated upholstered fabrics. Dermal permeation of expandable graphite applied on the polyester fabric showed no penetration after 24 h of fabric exposure time. This result demonstrated that graphite-treated polyester fabric is dermatologically and toxicologically safe for use in upholstery. Applied expandable graphite proved an efficient and safe flame-retardant alternative to conventional flame retardants for eco-friendly flame resistance applications in upholstery fabrics.

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“…The layer-by-layer (LbL) assembly technology has received more and more researchers' attention because of its green, environmental friendliness, and simplicity of operation. 27,28 Zhang and co-workers used LbL assembly technology to prepare GO multifunctional coating on flexible polyurethane foam, which significantly improves flame retardancy. The LbL assembly technique has been used in wide applications, such as oxygen barrier, drug delivery, electrochemical film, and sensing fields.…”

Section: Introductionmentioning

confidence: 99%

Graphene oxide/chitosan nano‐coating with ultrafast fire‐alarm response and flame‐retardant property

Yang

Yuan

Wang

et al. 2021

Polymers for Advanced Techs

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Using layer-by-layer self-assembly technology, an intelligent nano-coating was constructed on melamine foam (MF) by electrostatic interactions between chitosan (CS) molecules and graphene oxide (GO) nano-sheets. According to the principle that GO is quickly reduced to reduced GO under high temperature, a fast fire-warning network can be constructed. Due to the protective effect of nano-coating constructed on MF, the thermal stability and flame retardancy of melamine composite foams are improved. As the nano-coating self-assembly layer increases to 20, its flame-response time is only 3 s, and the continuous alarm time is as high as 1280 s.These indicate that the prepared GO-CS composite foam possesses excellent flame retardancy and super-fast fire response. This study provides a novel idea for the application of bio-based nano-coating in the fire early response and warning.

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A flame-retardant PET fabric coating: Flammability, anti-dripping properties, and flame-retardant mechanism

Cited by 55 publications

References 58 publications

Preparation and Test of UV Resistant and Flame Retardant Cotton Fabric With Phytic Acid, Tannic Acid and Diethylenetriamine as Raw Materials

Preparation and Test of UV Resistant and Flame Retardant Cotton Fabric With Phytic Acid, Tannic Acid and Diethylenetriamine as Raw Materials

Graphite flame retardant applied on polyester textiles: flammable, thermal and in vitro toxicological analysis

Graphene oxide/chitosan nano‐coating with ultrafast fire‐alarm response and flame‐retardant property

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