“…Headwater catchments influenced by volcanism in the tropical Andes provide many ecosystem services including erosion control, carbon sequestration, nutrient cycling, food provisioning, and production of high‐quality water (Aparecido et al, 2017; Mosquera et al, 2021; Wright et al, 2017). The latter is favoured by relatively low physical erosion rates (i.e., below 30 t km −2 year −1 , Tenorio et al, 2018, Vanacker et al, 2022) and sustained rainfall input throughout the year, often presenting no rain periods shorter than 2 weeks (Célleri et al, 2007), in combination with unique properties of soils formed from volcanic ash accumulation such as high organic matter content (i.e., up to above 53.6%, Nierop et al, 2007; Molina et al, 2019), and high‐water retention and infiltration capacities (Buytaert et al, 2005; Mosquera, Marín, et al, 2020). This water resource is crucial to support the development of urban centers such as Mérida, Bogotá, Cuenca, and Quito (Buytaert & De Bièvre, 2012).…”