A Facile Synthesis of Pure O<sub>2</sub>PtF<sub>6</sub>

Rudel, Stefan S.; Kraus, Florian

doi:10.1002/zaac.201500616

Cited by 6 publications

(2 citation statements)

References 16 publications

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“…The desired compound was formed (Figure S8, see the Supporting Information), but the yield was low. A much more facile synthesis of pure O 2 PtF 6 without the demanding synthesis of PtF 6 , or the use of high-pressure fluorination, has recently been reported …”

Section: Results and Discussionmentioning

confidence: 99%

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Syntheses of Dioxygenyl Salts by Photochemical Reactions in Liquid Anhydrous Hydrogen Fluoride: X-ray Crystal Structures of α- and β-O₂Sn₂F₉, O₂Sn₂F₉·0.9HF, O₂GeF₅·HF, and O₂[Hg(HF)]₄(SbF₆)₉

Mazej

Goreshnik

2020

Inorg. Chem.

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By treating gaseous, liquid, or solid fluorides with UV-photolyzed O2/F2 mixtures and by treating solid oxides with UV-photolyzed F2 (or O2/F2 mixtures) in liquid anhydrous HF at ambient temperature, we investigated the possibility of the preparation of O2MIIIF4 (M = B, Fe, Co, Ag), O2MIVF5 (M = Ti, Sn, Pb), (O2)2MIVF6 (M = Ti, Ge, Sn, Pb, Pd, Ni, Mn), O2MIV 2F9 (M = Sn), O2MVF6 (M = As, Sb, Au, Pt), O2MV 2F11 (M = Pt), O2MVIF7 (M = Se), (O2)2MVIF8 (M = Mo, W), and O2MVIIF8 (M = I). The approach has been successful in the case of previously known O2BF4, O2MF6 (M = As, Sb, Au; Pt), O2GeF5, and (O2)2(Ti7F30). Novel compounds O2GeF5·HF, α-O2Sn2F9 (1-D), and the HF-solvated and nonsolvated forms of β-O2Sn2F9 (2-D) were synthesized and their crystal structures determined using single-crystal X-ray diffraction. The crystal structures of all of these materials arise from the condensation of octahedral MF6 (M = Ge, Sn) units. The anion in the crystal structure of O2GeF5·HF is comprised of infinite ([GeF5]−)∞ chains of GeF6 octahedra that share common vertices. The HF molecules and O2 + cations are located between the chains. The crystal structure of α-O2SnF9 (1-D) is constructed from [O2]+ cations and polymeric ([Sn2F9]−)∞ anions which appear as two parallel infinite chains comprised of SnF6 units, where each SnF6 unit of one chain is connected to a SnF6 unit of the second chain through a shared fluorine vertex. The single-crystal structure determination of [O2][Sn2F9]·0.9HF reveals that it is comprised of two-dimensional ([Sn2F9]−)∞ grids with [O2]+ cations and HF molecules located between them. The 2-D grids have a wavelike conformation. The ([Sn2F9]−)∞ layer contains both six- and seven-coordinated Sn(IV) atoms that are interconnected by bridging fluorine atoms. A new, more complex [O2]+ salt, O2[Hg(HF)]4[SbF6]9, was prepared. In its crystal structure, the Hg atoms bridge to SbF6 units to form a 3-D framework. The O2 + cations are located inside the voids while the HF molecules are bound to Hg atoms through the F atom. Attempts to prepare several chlorine analogues of O2 + fluorine salts (i.e., O2TiCl5 and O2MCl6 (M = Nb, Sb)) failed.

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Section: Results and Discussionmentioning

confidence: 99%

“…A much more facile synthesis of pure O 2 PtF 6 without the demanding synthesis of PtF 6 , or the use of high-pressure fluorination, has recently been reported. 44 Attempted Syntheses of O 2 M V 2 F 11 (M = Pt). In addition to O 2 M VI F 6 , O 2 M V 2 F 11 is the second most prevalent group of O 2 + salts that is described in the literature.…”

Section: T H Imentioning

confidence: 99%

Syntheses of Dioxygenyl Salts by Photochemical Reactions in Liquid Anhydrous Hydrogen Fluoride: X-ray Crystal Structures of α- and β-O₂Sn₂F₉, O₂Sn₂F₉·0.9HF, O₂GeF₅·HF, and O₂[Hg(HF)]₄(SbF₆)₉

Mazej

Goreshnik

2020

Inorg. Chem.

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Fluorides: Inorganic Solid‐State and Structural Chemistry

Kraus

2024

Encyclopedia of Inorganic and Bioinorganic Chemistry

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After an introduction of what is special in solid‐state fluorine chemistry, different synthetic methods relevant to the field are discussed. These span the whole range from classical solid‐state syntheses, over synthesis in solution to gas‐phase synthesis including modern tools like photochemistry. The following structural chemistry section explains the crystal structures and their structural relationships among selected binary, ternary, and quaternary fluorides. A discussion on the physical properties of fluorides such as magnetism, electrical conductivity, ionic conductivity, fluoride ion batteries, and phosphors for light‐emitting diodes (LEDs) follows. We close with a chapter called “Beyond the Standard—I Oxidation State of Fluorine” where the existence of elemental F 2 on planet Earth is explained and ways to putative polyfluorides are presented.

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Über Oxidationszahl‐Obergrenzen in der Chemie

et al. 2018

Angewandte Chemie

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The concept of oxidation state OS is based on the Lewis electron-pair picture, assigning all bonding electrons to the more electronegative element. It is useful for bookkeeping the electrons, predicting chemical trends and inspiring synthetic chemists. A survey of experimental and quantum-chemical data reveals a limit near +8 for the highest OS in stable neutral chemical compounds under ambient conditions. OS = +9 was observed for isolated [IrO4] + cations in vacuum. The predicted existence of OS = +10 in a Pt compound is still to be verified experimentally. A high OS may involve the metal becoming electronegative and the O −2 ligands losing their closed-shell character as O −1 .

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A Facile Synthesis of Pure O₂PtF₆

Cited by 6 publications

References 16 publications

Syntheses of Dioxygenyl Salts by Photochemical Reactions in Liquid Anhydrous Hydrogen Fluoride: X-ray Crystal Structures of α- and β-O₂Sn₂F₉, O₂Sn₂F₉·0.9HF, O₂GeF₅·HF, and O₂[Hg(HF)]₄(SbF₆)₉

Syntheses of Dioxygenyl Salts by Photochemical Reactions in Liquid Anhydrous Hydrogen Fluoride: X-ray Crystal Structures of α- and β-O₂Sn₂F₉, O₂Sn₂F₉·0.9HF, O₂GeF₅·HF, and O₂[Hg(HF)]₄(SbF₆)₉

Fluorides: Inorganic Solid‐State and Structural Chemistry

Über Oxidationszahl‐Obergrenzen in der Chemie

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A Facile Synthesis of Pure O2PtF6

Cited by 6 publications

References 16 publications

Syntheses of Dioxygenyl Salts by Photochemical Reactions in Liquid Anhydrous Hydrogen Fluoride: X-ray Crystal Structures of α- and β-O2Sn2F9, O2Sn2F9·0.9HF, O2GeF5·HF, and O2[Hg(HF)]4(SbF6)9

Syntheses of Dioxygenyl Salts by Photochemical Reactions in Liquid Anhydrous Hydrogen Fluoride: X-ray Crystal Structures of α- and β-O2Sn2F9, O2Sn2F9·0.9HF, O2GeF5·HF, and O2[Hg(HF)]4(SbF6)9

Fluorides: Inorganic Solid‐State and Structural Chemistry

Über Oxidationszahl‐Obergrenzen in der Chemie

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A Facile Synthesis of Pure O₂PtF₆

Syntheses of Dioxygenyl Salts by Photochemical Reactions in Liquid Anhydrous Hydrogen Fluoride: X-ray Crystal Structures of α- and β-O₂Sn₂F₉, O₂Sn₂F₉·0.9HF, O₂GeF₅·HF, and O₂[Hg(HF)]₄(SbF₆)₉

Syntheses of Dioxygenyl Salts by Photochemical Reactions in Liquid Anhydrous Hydrogen Fluoride: X-ray Crystal Structures of α- and β-O₂Sn₂F₉, O₂Sn₂F₉·0.9HF, O₂GeF₅·HF, and O₂[Hg(HF)]₄(SbF₆)₉