Water pollution caused by petroleum and other organic compound spills has become a threat to biological and human safety. 1,2 In recent years, the materials for oil/water separation have been broadly explored. [3][4][5] Nature-inspired superwettable materials attracted lots of attention, which can selectively let oil or water pass through thus effectively separate oil and water. 6-10 Among them, the porous foam with hydrophobic and oleophilic properties can absorb and store organic compounds and repel water, thus achieving the highly efficient separation of oil/water mixtures. 11,12 Meanwhile, the cost of raw materials should be low to meet the requirements for mass production and applications.According to the Wenzel and Cassie models, the superhydrophobic property can be improved by increasing the surface roughness and reducing the surface energy. [13][14][15] Therefore, lots of organic compounds with low surface energy have been synthesized and employed for achieving the superhydrophobic property. 16 Among them, polyvinylidene fluoride (PVDF) has been widely used as the main building block in preparing the functional membranes for the oil/water separation, due to its chemical resistance, low surface energy (25 dynes/cm) as well as excellent mechanical properties. [17][18][19][20]