Abstract:Inorganic macrocycles remain largely underdeveloped compared with their
organic counterparts due to the challenges involved in their synthesis. Among
them, cyclodiphosphazane macrocycles have shown to be promising candidates for
supramolecular chemistry applications. However, further developments have been
handicapped by the lack of synthetic routes to high-order cyclodiphosphazane
macrocycles. Here we report the synthesis of high-order oxygen-bridged
phosphazane macrocycles via a “3+n” (n= 1 and 3) condensati… Show more
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