We put forward one of the forms of functional pentagon equation (FPE), known from the theory of integrable models, as an algebraic explanation to the phenomenon known in physics as s ↔ t duality. We present two simple geometrical examples of FPE solutions, one of them yielding in a particular case the well-known Veneziano expression for 4-particle amplitude. Finally, we interpret our solutions of FPE in terms of relations in Lie groups.