A dithiocarbazate N,S Schiff base ligand with a long alkyl chain: Synthesis, characterization, DFT study and antimicrobial activity of its Ni(II) complex

Begum, Marium; Das, Dipto; Zangrando, Ennio; Rahman, Shofiur; Alodhayb, Abdullah; Begum, Mst. Khurshida; Sheikh, Chan Miya; Miyatake, Ryuta; Howlader, M. B. H.; Karim, Md. Rabiul; Chowdhury, Md. Belal

doi:10.1016/j.molstruc.2022.134808

Cited by 3 publications

(3 citation statements)

References 49 publications

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“…Correspondingly the N2-C9 bond of 1.340 (4) A ˚in HL shortens to essentially double bonds of 1.293 (3) and 1.290 (2) A ˚in the complex, while the N1-N2 bond length of 1.377 (4) A ˚is slightly elongated in the complex [to 1.414 (2) and 1.417 (2) A ˚, see the supporting information]. These parameters agree with those in previously reported Ni II complexes with similar ligands (Begum et al, 2016(Begum et al, , 2017(Begum et al, , 2020(Begum et al, , 2023Howlader et al, 2015;Islam et al, 2014;Khan et al, 2023;Zangrando et al, 2015). Upon coordination the ligand L undergoes a rotation of ca.…”

Section: Structural Commentarysupporting

confidence: 90%

“…Numerous Ni II complexes with dithiocarbazate ligands have been reported from these laboratories (Begum et al, 2016(Begum et al, , 2017(Begum et al, , 2020(Begum et al, , 2023Howlader et al, 2015;Islam et al, 2014;Khan et al, 2023;Zangrando et al, 2015; CSD refcodes = JUYCAJ, WEGKEB, TILVUJ, PICMOH, LUBYAK, MIXRAO, MIMKIG and LUBNON, respectively).…”

Section: Database Surveymentioning

confidence: 99%

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Crystal structure of S-n-octyl 3-(1-phenylethylidene)dithiocarbazate and of its bis-chelated nickel(II) complex

Khan,

Howlader,

Sheikh

et al. 2023

Acta Cryst E

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The nitrogen–sulfur Schiff base proligand S-n-octyl 3-(1-phenylethylidene)dithiocarbazate, C17H26N2S2 (HL), was prepared by reaction of S-octyl dithiocarbamate with acetophenone. Treatment of HL with nickel acetate yielded the complex bis[S-n-octyl 3-(1-phenylethylidene)dithiocarbazato]nickel(II), [Ni(C17H25N2S2)2] (NiL 2), which was shown to adopt a tetrahedrally distorted cis-square-planar coordination geometry, with the NiSN planes of the two ligands forming a dihedral angle of 21.66 (6)°. Changes in the geometry of the L ligand upon chelation of Ni2+ are described, involving a ca 180° rotation around the N(azomethine)—C(thiolate) bond.

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Section: Structural Commentarysupporting

confidence: 90%

Section: Database Surveymentioning

confidence: 99%

Crystal structure of S-n-octyl 3-(1-phenylethylidene)dithiocarbazate and of its bis-chelated nickel(II) complex

Khan,

Howlader,

Sheikh

et al. 2023

Acta Cryst E

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“…For comparison, Ni II complexes with comparable ligands bearing long alkyl chains have been reported from these laboratories (Begum et al, 2016(Begum et al, , 2017(Begum et al, , 2018(Begum et al, , 2020(Begum et al, , 2023; CSD refcodes = JUYCAJ, WEGKEB, BIQTIH, TILVUJ and PICMOH, respectively).…”

Section: Database Surveymentioning

confidence: 87%

Crystal structure of bis{S-octyl-3-[(thiophen-2-yl)methylidene]dithiocarbazato-κ² N ³,S}nickel(II)

Khan,

Howlader,

Sheikh

et al. 2023

Acta Cryst E

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In the title complex, [Ni(C14H21N2S3)2], the nickel(II) atom is located on a crystallographic inversion center and exhibits a square-planar coordination environment, being coordinated by two negatively charged N,S-chelating ligands in a trans configuration. In the crystal, the non-H atoms of the complex are practically coplanar (r.m.s. deviation of fitted atoms = 0.135 Å), and the angle between the thienyl and the chelating rings is 6.7 (1)°. The molecules stack at a distance of 3.623 (2) Å along the b-axis direction.

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Fluorescence property and solvent effect on m-bromosalicylaldehyde derivative; insights from synthesis, characterization, antimicrobial activity and computational studies

Priya,

Venkatraman,

Sowrirajan

et al. 2023

Chemical Physics Impact

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A dithiocarbazate N,S Schiff base ligand with a long alkyl chain: Synthesis, characterization, DFT study and antimicrobial activity of its Ni(II) complex

Cited by 3 publications

References 49 publications

Crystal structure of S-n-octyl 3-(1-phenylethylidene)dithiocarbazate and of its bis-chelated nickel(II) complex

Crystal structure of S-n-octyl 3-(1-phenylethylidene)dithiocarbazate and of its bis-chelated nickel(II) complex

Crystal structure of bis{S-octyl-3-[(thiophen-2-yl)methylidene]dithiocarbazato-κ² N ³,S}nickel(II)

Fluorescence property and solvent effect on m-bromosalicylaldehyde derivative; insights from synthesis, characterization, antimicrobial activity and computational studies

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A dithiocarbazate N,S Schiff base ligand with a long alkyl chain: Synthesis, characterization, DFT study and antimicrobial activity of its Ni(II) complex

Cited by 3 publications

References 49 publications

Crystal structure of S-n-octyl 3-(1-phenylethylidene)dithiocarbazate and of its bis-chelated nickel(II) complex

Crystal structure of S-n-octyl 3-(1-phenylethylidene)dithiocarbazate and of its bis-chelated nickel(II) complex

Crystal structure of bis{S-octyl-3-[(thiophen-2-yl)methylidene]dithiocarbazato-κ2 N 3,S}nickel(II)

Fluorescence property and solvent effect on m-bromosalicylaldehyde derivative; insights from synthesis, characterization, antimicrobial activity and computational studies

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Crystal structure of bis{S-octyl-3-[(thiophen-2-yl)methylidene]dithiocarbazato-κ² N ³,S}nickel(II)