In recent years, energy harvesting technology has become a promising power supply method for low-power wireless sensor nodes. According to the application requirements of energy acquisition, a piezoelectric and electrostatic hybrid vibration energy harvester is proposed in this paper. Compared with other vibration energy harvesters, the proposed hybrid harvester is easier to miniaturize and integrate into a Micro-Electro-Mechanical System (MEMS). The electromechanical coupling model of the hybrid harvester is established. The optimal design of the proposed harvester is carried out based on numerical simulation. The optimal matching impedance of piezoelectric and electrostatic modules are calculated based on numerical simulation and validated through experiments, which are 80-90 kΩ and 15-20 MΩ, respectively. The output power of the hybrid vibration energy harvester is increased by 0.04%, 0.08%, 0.102%, and 0.097%, when the excitation acceleration is 0.1 g, 0.15 g, 0.2 g, and 0.25 g, respectively, compared with the single piezoelectric module.