ZnO has many potential applications, such as, solar cells, photocatalysts, chemical sensors and biosensors. However, to extend its visible light response is still a great challenge. In this paper, ZnO nanosheets were prepared by a wet chemical method. The surface treatment of ZnO nanosheets was carried out using chloroauric acid, and then reduced with aniline. A series of characterisations were examined by TEM (transmission electron microscopy), XRD (X-ray diffraction), the Fourier transform infrared (FTIR) spectra and ultraviolet-visible spectroscopy (UVvis). The experimental results indicated that ZnO nanosheets modified with a thin layer of Au/PANi composite exhibited wide visible light response. A chemical prototype sensor was constructed based on the ZnO/Au/polyaniline nanocomposites prepared and interdigital electrodes on flexible polymer substrates. The effects of surface treatment of ZnO nanosheets on the gas sensing behaviours were examined. The results indicated that the effective conductive channels for charge transfer and separation were formed due to the Au/polyaniline necklaces attached on the surface of ZnO nanosheets, and the type of conductivity of ZnO/Au/polyaniline nanocomposite changed to P-type from N-type with increasing the amounts of chloroauric acid. When the synthesis parameter of ZnO/Au/polyaniline nanocomposite was optimised, the gas sensitivity of ZnO/Au/PANi (polyaniline) was superior to that of PANi nanowire prepared under similar synthesis condition, and it has been found that this kind of nanocomposite not only possesses widening light response, harvests more visible light, but also presents effective channels for charge transfer. It would be useful in potential applications in photocatalysts or other fields.