“…Tremendous efforts have been devoted to develop high-efficiency flexible solar cells in recent years to meet the energy demands of various moving objects, wearable devices, and buildings with curved surfaces. − Of the flexible thin-film solar cells, flexible lead halide perovskite solar cells (PSCs) have gained worldwide attention owing to their low cost and high power conversion efficiencies (PCEs). − Though the state-of-art PCE of the flexible single-junction PSC has been reported as 20.01%, further enhancement is required as the champion PCE of flexible CuIn 1– x Ga x Se 2 solar cells has already exceeded 20%. , Defects within the perovskite absorber play a crucial role in determining the PCEs of PSCs, especially those of the flexible PSC. Those defects are inevitably distributed at the surface and grain boundaries or in the bulk of the perovskite films, which not only result in nonradiative charge recombination and limited PCEs but also cause the rapid degradation of the perovskite absorber. − For the flexible PSC, the defects are more likely to form owing to the low surface energy, the wrinkle of the flexible substrates. , …”