In this paper we study the Heat Flow on Metric Random Walk Spaces, which unifies into a broad framework the heat flow on locally finite weighted connected graphs, the heat flow determined by finite Markov chains and some nonlocal evolution problems. We give different characterizations of the ergodicity and we also prove that a metric random walk space with positive Ollivier-Ricci curvature is ergodic. Furthermore, we prove a Cheeger inequality and, as a consequence, we show that a Poincaré inequality holds if and only if an isoperimetrical inequality holds. We also study the Bakry-Émery curvature-dimension condition and its relation with functional inequalities like the Poincaré inequality and the transport-information inequalities. µ * m(A) := X m x (A)dµ(x), for all Borel sets A ⊂ X,