In this paper, the effects of electron beam on the X pinch produced spectra of L-shell Mo plasma have been investigated by principal component analysis (PCA), and this analysis is compared with that of line ratio diagnostics. Spectral database for PCA extraction was arranged using the non-LTE collisional radiative L-shell Mo model. PC vector spectra of L shell Mo including F, Ne, Na and Mg-like transitions were studied to investigate the polarization types of these transitions. PC1 vector spectra of F, Ne, Na and Mg-like transitions resulted in linear polarization of Stokes Q profiles. Besides, PC2 vector spectra showed linear polarization of Stokes U profiles of 2p 5 3s of Ne like transitions which were recognized as responsive to the magnetic field (Trabert et al., 2017). 3D representation of PCA coefficients demonstrated that addition of electron beam to the non-LTE model generates the quantized collective clusters which are translations of each other and follow Vshaped cascade trajectories except for the case f = 0.0. The extracted principal coefficients were used as a database for the Artifical Neural Network (ANN) to estimate the plasma electron temperature, density and beam fractions of time integrated spatially resolved L-shell Mo X-pinch plasma spectrum. PCA based ANN provides advantage in reducing the network topology with a more efficient Backpropagation supervised learning algorithm. The modeled plasma electron temperature is about T e~6 60 eV and density n e =1x10 20 cm -3 in the presence of the fraction of the beams with f~0.1 and centered energy of 5 keV.