A critical discussion on the analysis of buried interfaces in Li solid-state batteries. Ex situ and in situ/operando studies

López, Isidoro; Morey, Julien; Ledeuil, Jean Bernard; Madec, Lénaïc; Martínez, Hervé

doi:10.1039/d1ta04532f

Cited by 15 publications

(10 citation statements)

References 181 publications

(248 reference statements)

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“…To analyse ex situ the buried interfaces of SSBs using surface analytical techniques, it is mandatory to reveal these interfaces in a first step. However, numerous literature reports rely on the manual ability of a researcher to separate mechanically the interfaces [5], [14]- [16]. Here, we will show that even for polymerbased SSBs, the use of Ar + ion milling (i.e.…”

Section: Ex Situ Analysis Of Buried Interfaces In Ssbsmentioning

confidence: 85%

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Methodological developments to expose and analyse buried interfaces in lithium solid-state batteries using ex situ, in situ and operando cycling

Morey

Ledeuil²,

Madec³

et al. 2022

EPJ Web Conf.

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Lithium solid-state batteries (SSBs) are a promising technology for electrochemical energy storage systems. So far, the performance of SSBs are mainly governed by the electro-chemo-mechanical properties of the diverse solid/solid interfaces and their evolution upon cycling. However, as these interfaces are buried in the battery stack, their comprehensive understanding remains a challenge. Here, we thus provide some advances in methodological developments for ex situ, in situ and operando cycling/analysis of these buried interfaces. It is showed that noble gaz ion milling at liquid nitrogen temperature is a suitable and reproducible method to prepare cross-section without any chemical/physical change even for polymer-based SSBs. In addition, innovative operando cycling using Auger analysis was proposed for the first time on a model Li/Li6PS5Cl stack. The interest of this approach is to be able to proceed without a dedicated electrochemical cell and to use the fully adjustable electron beam of the auger to create a surface potential difference followed by lithium migration then SEI (Solid Electrolyte Interface) formation and Li plating. Overall, this work should greatly benefits to all researchers working on buried interfaces study in lithium solid-state batteries.

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Section: Ex Situ Analysis Of Buried Interfaces In Ssbsmentioning

confidence: 85%

“…Thus, improvement of SSBs electrochemical performance will be achieved through a comprehensive understanding of the interphases electro-chemomechanical properties upon cycling. [4], [5] As illustrated in Fig. 1, a significant number of interfaces are identified in SSBs.…”

Section: Introductionmentioning

confidence: 99%

Methodological developments to expose and analyse buried interfaces in lithium solid-state batteries using ex situ, in situ and operando cycling

Morey

Ledeuil²,

Madec³

et al. 2022

EPJ Web Conf.

Self Cite

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“…Finally, the development of new in-situ characterization technology is beneficial to observe the growth of dendrites, and then guide the design of dendrite suppression. [140][141][142]…”

Section: Discussionmentioning

confidence: 99%

NASICONs‐type solid‐state electrolytes: The history, physicochemical properties, and challenges

Zhang

Liu

You

et al. 2022

Interdisciplinary Materials

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Solid‐state electrolytes are critical for the development of next‐generation high‐energy and high‐safety rechargeable batteries. Among all the candidates, sodium (Na) superionic conductors (NASICONs) are highly promising because of their evident advantages in high ionic conductivity and high chemical/electrochemical stability. The concept of NASICONs was proposed by Hong and Goodenough et al. in 1976 by reporting the synthesis and characterization of Na1+xZr2(SixP3−x)O12 (0 ≤ x ≤ 3), which has attracted tremendous attention on the NASICONs‐type solid‐state electrolytes. In this review, we are committed to describing the development history of NASICONs‐type solid‐state electrolytes and elucidating the contribution of Goodenough as a tribute to him. We summarize the correlations and differences between lithium‐based and sodium‐based NASICONs electrolytes, such as their preparation methods, structures, ionic conductivities, and the mechanisms of ion transportation. Critical challenges of NASICONs‐structured electrolytes are discussed, and several research directions are proposed to tackle the obstacles toward practical applications.

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“…5.1 Sample preparations and in situ/operando cell constructions In situ and operando techniques are widely used for all-solidstate batteries. [86][87][88][89] Microscopy is a simple but powerful tool to investigate the reaction mechanism through the direct observation of cells. Similar to optical microscopy, Raman spectroscopy is conducted using objective lenses, and therefore, these measurements use similar in situ/operando cells.…”

Section: Raman Spectroscopy and Microscopy For All-solid-state Batteriesmentioning

confidence: 99%

Electrochemical In Situ/operando Spectroscopy and Microscopy Part 2: Battery Applications

et al. 2022

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In situ/operando techniques for electrochemical systems are useful for understanding the electrochemical reactions, as we presented in Part 1. Here we present a series of in situ/operando techniques for battery applications. Now the in situ/operando techniques presented in this paper has become powerful tools for the development of advanced battery systems such as Li-ion batteries, solid-state batteries, and other beyond Li-ion batteries. In the present paper we introduce the in situ/operando cell design of each measurement technique and discuss how we apply each technique for in the advanced battery materials development.

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A critical discussion on the analysis of buried interfaces in Li solid-state batteries. Ex situ and in situ/operando studies

Abstract: Interfacial electro-chemo-mechanical phenomena determine the performance of Li solid-state batteries (SSBs), thus the study of these processes is key to construct more efficient and stable systems. In this regard, the...

Cited by 15 publications

References 181 publications

Methodological developments to expose and analyse buried interfaces in lithium solid-state batteries using ex situ, in situ and operando cycling

Methodological developments to expose and analyse buried interfaces in lithium solid-state batteries using ex situ, in situ and operando cycling

NASICONs‐type solid‐state electrolytes: The history, physicochemical properties, and challenges

Electrochemical In Situ/<i>operando</i> Spectroscopy and Microscopy Part 2: Battery Applications

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