A Coupled System of Ni3S2 and Rh Complex with Biomimetic Function for Electrocatalytic 1,4-NAD(P)H Regeneration
Shujie Tian,
Guifa Long,
Panwang Zhou
et al.
Abstract:NAD(P)H cofactor is a critical energy and electron carrier
in biocatalysis
and photosynthesis, but the artificial reduction of NAD(P)+ to regenerate bioactive 1,4-NAD(P)H with both high activity and
selectivity is challenging. Herein, we found that a coupled system
of a Ni3S2 electrode and a Rh complex in an
electrolyte (denoted as Ni3S2-Rh) can catalyze the reduction of NAD(P)+ to 1,4-NAD(P)H
with superior activity and selectivity. The optimized selectivity
in 1,4-NADH can be up to 99.1%, much higher than tha… Show more
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