A correction method for the incomplete dissociation of sulfuric acid in the Villermaux-Dushman reaction system

Shang, R.; Zhu, Yu-Gan; Liang, Chuang; Liu, Zhihao; Chu, Guang‐Wen

doi:10.1016/j.cep.2023.109504

Cited by 2 publications

(1 citation statement)

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“…The commonly employed acids for the Villermaux–Dushman reaction include sulfuric acid and perchloric acid. ,,, For the present study, sulfuric acid was selected due to its widespread availability and safety advantages . However, it is important to note that sulfuric acid does not completely dissociate. , Neglecting this fact and assuming full dissociation of sulfuric acid in the test reaction environment would considerably compromise the accuracy of the calculations and modeling.…”

Section: Methodsmentioning

confidence: 99%

Micromixing in a Novel Microannular Rotating Bed

Zhang,

Xue,

Liu

et al. 2024

Ind. Eng. Chem. Res.

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Microchannel reactors have garnered significant attention in various chemical processes due to their ability to achieve rapid mixing. However, there remains ample opportunity for the development of microchannel reactors with simple structures and high throughput. In this work, we propose a novel microannular rotating bed (MARB) that integrates the high-gravity field and microscale effect to enhance the micromixing efficiency. The Villermaux−Dushman reaction system is employed to investigate the influence of the operating parameters on the mixing performance. The micromixing time of the MARB ranges from 10 −4 to 10 −3 s for low-viscosity Newtonian fluids and from 10 −4 to 10 −2 s for shear-thinning non-Newtonian fluids. In a lab-scale setup, the MARB demonstrates a throughput of 6 L/min, markedly surpassing the capabilities of the existing microchannel reactors. Furthermore, the evaluation of energy dissipation rate underscores the MARB's remarkable energetic efficiency in intensifying mixing processes. The MARB, with its simple design, high throughput capacity, and efficiency, presents a promising alternative for the intensification of mixing across diverse chemical applications.

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