Phys. Chem. Chem. Phys.
 2024
DOI: 10.1039/d3cp05406c
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A confinement-regulated (H3C–NH3)+ ion as a smallest dual-wheel rotator showing bisected rotation dynamics

Wang Li,
Miao Xie,
Shi-Yong Zhang
et al.

Abstract: On the basis of the variable-temperature single-crystal X-ray diffraction, rotational energy barrier analysis, variable-temperature/frequency dielectric response, and molecular dynamics simulations, here we report a new crystalline supramolecular rotor (CH3NH3)(18-crown-6)[CuCl3], in...

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