A Computational Study of the Intermolecular Interactions in the Head-To-Tail Arrangement of the 5CB Liquid Crystal Monomers
Luis Humberto Mendoza-Huizar,
Eduardo García Sánchez,
Luis Octavio Solís Sánchez
Abstract:In the present work, we have analyzed the molecular interactions existing in a 4-n-pentyl-4-cyano-biphenyl (5CB) monomer and its dimer, in the head-tail configuration. The optimized geometrical structures of the monomer and dimer were obtained using the theoretical level wB97-XD/6-311G++(d,p). The intermolecular interactions were analyzed through the non-covalent interaction index (NCI) and the localized molecular orbital energy decomposition analysis method (LMO-EDA). Our results suggest that the antiparallel… Show more
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