A comprehensive review of the influence of particle size and pore distribution on the kinetics of CO₂ hydrate formation in porous media

Abstract

As an essential greenhouse gas, CO2 is the leading cause of global warming and environmental problems. An efficient strategy to lower CO2 emissions is the hydrate‐based method of CO2 geological storage. The stability and formation process of hydrate is the premise and foundation of the hydrate method of CO2 geological storage. However, the formation rule of CO2 hydrate has a significant impact on the formation characteristics of CO2 hydrate. This paper thoroughly examines the formation properties of CO2 hydrate in porous media systems. The quantitative impacts and laws of many parameters on the CO2 hydrate production process are thoroughly examined. On this basis, the internal mechanism of particle size, pore distribution, and critical size of particles in porous media systems on the kinetics of CO2 hydrate formation are detailed. Finally, the shortcomings of the studies on CO2 hydrate formation kinetics in porous media systems and the main directions in the future are pointed out. The influence of pore distribution in porous media on the CO2 hydrate formation process still needs further study. The relative results will be useful in the future for CO2 capture and sequestration in sediments. © 2023 Society of Chemical Industry and John Wiley & Sons, Ltd.

Crystal Growth of Clathrate Hydrate Formed with Carbon Dioxide and Deuterium Oxide: Implications for Hydrate-based Tritium Separation

“…Meanwhile, the utilization of the CO 2 gas may require a high-pressure container for hydrate formation. The kinetics of CO 2 hydrate formation has widely been investigated for various applications. − …”