Improving the flow field uniformity of catalytic converter can promote the catalytic conversion of NO to NO2. Firstly, the physical and mathematical models of improved catalytic converter are established, and its accuracy is verified by experiments. Then, the NO catalytic performance of standard and improved catalytic converters is compared, and the influences of structural parameters on its performance are investigated. The results showed that: (1) The gas uniformity, pressure drop and NO conversion rate of the improved catalytic converter are increased by 0.0643, 6.78% and 7.0% respectively. (2) As the cell density combination is 700 cpsi/600 cpsi, NO conversion rate reaches the highest, 73.7%, and the gas uniformity is 0.9821. (3) When the tapered height is 20 mm, NO conversion rate reaches the highest, 72.4%, the gas uniformity is 0.9744. (4) When the high cell density radius is 20 mm, NO conversion rate reaches the highest, 72.1%, the gas uniformity is 0.9783. (5) When the tapered end face radius is 20 mm, NO conversion rate reaches the highest, 72.0%, the gas uniformity is 0.9784. The results will provide a very important reference value for improving NO catalytic and reducing vehicle emission.