2013
DOI: 10.1016/j.carbon.2012.09.051
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A composite material made of carbon nanotubes partially embedded in a nanocrystalline diamond film

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Cited by 18 publications
(11 citation statements)
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“…While the concentration of catalyst precursor increases further, in agreement with the cases at 500 C and 550 C, R declines signicantly. This phenomenon may be caused by intensive diffusion of catalyst atoms into carbon bers at a high temperature of 600 C or higher, which leads to that the smaller catalyst particles formed on the surface of carbon ber due to the lower concentration of catalyst precursor will easily diffuse into carbon bers and become less active or even deactivated, 46,47 therefore, the amount of catalyst that remains active for the synthesis of CNTs on carbon bers decreases with the reduction of the concentration, it leads to the low R for the case of low catalyst precursor concentration. When the concentration of catalyst precursor is c 0 or higher, the large catalyst particles are formed, which results in that the effect of diffusion of catalyst particles into bers on their activity is very low, the variations of R with c match well with the conclusion of CNT/CNF growth model.…”
Section: Mathematic Model For Cnt/cnf Growth On the Surface Of Carbon...mentioning
confidence: 99%
“…While the concentration of catalyst precursor increases further, in agreement with the cases at 500 C and 550 C, R declines signicantly. This phenomenon may be caused by intensive diffusion of catalyst atoms into carbon bers at a high temperature of 600 C or higher, which leads to that the smaller catalyst particles formed on the surface of carbon ber due to the lower concentration of catalyst precursor will easily diffuse into carbon bers and become less active or even deactivated, 46,47 therefore, the amount of catalyst that remains active for the synthesis of CNTs on carbon bers decreases with the reduction of the concentration, it leads to the low R for the case of low catalyst precursor concentration. When the concentration of catalyst precursor is c 0 or higher, the large catalyst particles are formed, which results in that the effect of diffusion of catalyst particles into bers on their activity is very low, the variations of R with c match well with the conclusion of CNT/CNF growth model.…”
Section: Mathematic Model For Cnt/cnf Growth On the Surface Of Carbon...mentioning
confidence: 99%
“…In these studies the CNTs are grown by the socalled "base growth method" where the metal catalyst particles remain attached to the diamond surface due to strong CNT/diamond adhesion forces [11][12] . Disadvantageously, the remaining metal particles in the final multi-layer composite structure may negatively affect their electromechanical properties 11 .…”
Section: Introductionmentioning
confidence: 99%
“…On fibres and other carbon-based materials, however, control over CNT CVD remains challenging [14]. This is because the process involves catalyst formation/activation at $600 to 800°C, and, at these temperatures, the metal catalysts may diffuse/ react with the carbon-based supports [15]. The interaction often leads to catalyst diffusion and/or poisoning and ultimately causes poor/no growth [16].…”
Section: Introductionmentioning
confidence: 99%