The present paper deals with investigation of the possibility for application of laser welding-on technology for repairing the mold cavities of die casting dies. The surface of the samples, made of 32CrMoV12-28 (DIN) steel, was welded on by additional material -maraging alloy with chemical composition 0.02С-19.3Ni -0.4V-2Cr-14.5Co-4.7Mo-0.25Al-0.2Mn-0.2Si, (wt %). The surface treatment was done by pulse laser AL 200 Nd:YAG with a wave length of 1064 nm. To estimate the possibility for additional hardening of the welded-on layers, the samples were heated for 1 hour at temperatures of 450, 500, 550 and 600 °С. The microstructure was investigated by light microscopy, the Vickers microhardness was measured with 100 g load and XRD-analysis was done. After laser welding-on the hardened surface layer was obtained. Its microstructure possesses dendrite morphology and consists mainly of ferrite oversaturated with alloying elements. The intermetallic compounds of the types Fe-Cr and Fe-Al are also observed. After ageing Ni-Al and Ni-Mo phases precipitate with maximal quantity at a temperature of 550 °C. After ageing at this temperature a maximal hardness of 600-650 HV, twice higher than that of the welded-on layer, was observed. The next temperature increase leads to the hardness decrease up to 400-450 HV due to the interruption of the coherent bonds between the phases and transformation of dendrite morphology to equiaxed crystals. As a result of the present investigation the application of the laser welding-on with additional material -maraging alloy, could be recommended for repairing the mold cavities of die casting dies.