A Comparison of Cooking Conditions of Rhizoclonium Pulp as a Substitute for Wood Pulp

Abstract

The green macroalga Rhizoclonium was cooked with 5%, 10%, and 20% sodium hydroxide (NaOH) for 4 h (5-N, 10-N, and 20-N groups, respectively); with 5%, 10%, and 20% sodium sulfite (Na2SO3) for 4 h (5-NS, 10-NS, and 20-NS groups, respectively); and with 5%, 10%, and 20% NaOH for 2 h and 1% hydrogen peroxide (H2O2) for 2 h (5-NH, 10-NH, and 20-NH groups, respectively). The 5-NH handsheet showed the best mechanical properties; however, the 10-NH pulp was easier to separate than 5-NH during handsheet making, and 10-NH was more suitable for the industrial process. Thus, the 10-NH group showed the optimal production conditions with an optimal length/width ratio, crystallinity index (CI%), three-dimensional (3D) configuration, and mechanical strength. Substituting 20% 10-NH Rhizoclonium pulp with wood pulp had no significant effect on the mechanical properties of the 100% wood pulp handsheet. However, the fibers of the NS group were flatter and lost their 3D configuration, resulting in low mechanical strength. Overall, Rhizoclonium had its own optimal cooking condition, which was not the same as for wood pulp, and it has potential as a substitute for wood pulp in papermaking.

Experimental Study on the Manufacturing of Functional Paper with Modified by N-Methylmorpholine-N-oxide Surfaces

“…Currently, a large number of pulping options are proposed in the literature that allow for obtaining both alpha enriched (high molecular weight cellulose insoluble in 17.5% alkaline solution) and cellulose products containing dozens of percent of hemicelluloses or lignin [ 14 , 15 ]. The presence of hemicellulose in cellulose is often welcome in the manufacturing processes of paper and board.…”