A Comparison of Combustion Properties in Biomass–Coal Blends Using Characteristic and Kinetic Analyses

Abstract

This paper presents comparative research on the combustion of coal, wheat, corn straw (CS), beet residues after extracting sugar (BR), and their blends, coal–corn straw blends (CCSBs), coal–wheat blends (CWBs), and coal–beet residue blends (CBRBs), using thermogravimetric (TG) analysis under 10, 20, 30, 40 and 50 °C/min. The test results indicate that CS and wheat show better combustion properties than BR, which are recommended to be used in biomass combustion. Under the heating rate of 20 °C/min, the coal has the longest thermal reaction time when compared with 10 and 30 °C/min. Adding coal to the biomass can improve the burnout level of biomass materials (BM), reduce the burning speed, and make the reaction more thorough. The authors employed the Flynn–Wall–Ozawa (FWO) method and the Kissinger–Akahira–Sunose (KAS) method to calculate kinetics parameters. It was proven that overall, the FWO method is better than the KAS method for coal, BM, and coal–biomass blends (CBBs), as it provides higher correlations in this study. It is shown that adding coal to wheat and BR decreases the activation energy and makes conversion more stable under particular α. The authors selected a wider range of biomass raw materials, made more kinds of CBB, and conducted more studies on different heating rates. This research can provide useful insights into how to choose agricultural residuals and how to use them.

Effect of Anoxic Atmosphere on the Physicochemical and Pelletization Properties of Pinus massoniana Sawdust during Storage

“…The comprehensive combustibility index S N was used to characterize the combustion characteristics of samples. The detailed calculation method is introduced through the previous research [22,23].…”

Pyrolysis and Combustion Behavior of Flax Straw as Biomass: Evaluation of Kinetic, Thermodynamic Parameters, and Qualitative Analysis of Degradation Products

“…The intricate and diverse composition of biomass presents a challenge as various reactions can take place during the conversion process, and the degree of these reactions is dependent on numerous parameters and conditions [13]. Therefore, studying the thermal decomposition kinetics of biomass is crucial to finding the mechanism of the process, predict the conversion of it, and optimize reactor system design for efficient conversion [14].…”